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Title Sustainable catalysis, Without metals or other endangered elements. Part 2 / editor: Michael North
Published [Cambridge] : Royal Society of Chemistry, [2015]
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Description 1 online resource
Series RSC green chemistry ; 41
RSC green chemistry series ; 41
Contents 880-01 Cover; Contents; Preface; References; Part 2; Chapter 14 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Carbon Bond-forming Reactions ; 14.1 Introduction; 14.2 Catalytic Asymmetric 1,4-Addition Reactions; 14.3 Catalytic Asymmetric 1,2-Addition Reactions; 14.4 Catalytic Asymmetric Cycloaddition Reactions; 14.5 Concluding Remarks; References; Chapter 15 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Heteroatom Bond-forming Reactions ; 15.1 Introduction; 15.2 Hydrophosphonylation; 15.3 Epoxidation and Hydroperoxidation
880-01 18.1.1 Enamine Catalysis: Nucleophilicity of Imidazolidinone-derived Enamines: The Aldol Reaction18.1.2 Alkylation Reactions with Imidazolidinone Enamines; 18.2 α-Addition of Heteroatoms Catalysed by Imidazolidinone Organocatalysts ; 18.3 Iminium Activation with Imidazolidinones Organocatalysts; 18.3.1 Diels-Alder and [2+3] Dipolar-type Reactions with Imidazolidinone Catalysts; 18.3.2 Friedel-Crafts-type Reactions: Pyrroles, Indoles and N, N Dialkyl-substituted Anilines; 18.3.3 Mukaiyama-Michael Reaction Promoted by Imidazolidinone Organocatalysts
16.2.1 Monoalkylation of Schiff Bases Derived from Glycine16.2.2 Dialkylation of Schiff Bases Derived from Glycine; 16.2.3 Other Alkylations with Cinchona-derived PTC Catalysts; 16.2.4 Conjugate Additions with Cinchona-derived PTC Catalysts; 16.2.5 Aldol Reactions with Cinchona-derived PTC Catalysts; 16.2.6 Mannich Reactions with Cinchona-derived PTC Catalysts; 16.2.7 Darzens Reaction with Cinchona-derived PTC Catalysts; 16.2.8 Epoxidation of Enones with Cinchona-derived PTC Catalysts; 16.2.9 Other Reactions with Cinchona-derived PTC Catalysts; 16.3 Conclusions; References
Chapter 17 Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts 17.1 Introduction; 17.2 Design of Chiral Amine Catalysts; 17.2.1 Aldol Reactions; 17.2.2 Mannich Reactions; 17.2.3 Conjugate Additions; 17.2.4 C-O and C-N Bond Formations; 17.2.5 Halogenations; 17.3 Design of Chiral Phase-transfer Catalysts; 17.3.1 Alkylations; 17.3.2 Conjugate Additions; 17.3.3 Aldol and Mannich Reactions; 17.3.4 Strecker Reactions; 17.3.5 Oxidations; 17.4 Conclusions; References; Chapter 18 Imidazolidinones as Asymmetric Organocatalysts ; 18.1 Introduction
Summary Catalysis is a fundamentally sustainable process which can be used to produce a wide range of chemicals and their intermediates. Focussing on those catalytic processes which offer the most sustainability, this two-part book explores recent developments in this field, as well as examining future challenges. Focussing on catalysis without metals or other endangered elements, each chapter covers a different type of organocatalyst. Beginning with chapters on acid and base catalysis, the book then concentrates on asymmetric catalysis. Several chapters cover pyrrolidine-based and cinchona alkaloid-based catalysts, whilst other chapters examine further organoctalysts which are constructed only from sustainable elements. Together with Sustainable Catalysis: With Non-endangered Metals, these books examine the progress in sustainable catalysis in all areas of chemistry, and are an important reference for researchers working in catalysis and green chemistry
Notes Includes index
Bibliography Includes bibliographical references at the end of each chapters and index
Notes English
Online resource; title from title details screen (Royal Society of Chemistry, viewed November 19, 2015)
Print version record
Subject Catalysis.
Form Electronic book
Author North, Michael, 1964- editor
ISBN 1523102004 (electronic bk.)
1782626433 (electronic bk.)
1782627537 (electronic bk.)
9781523102006 (electronic bk.)
9781782626435 (electronic bk.)
9781782627531 (electronic bk.)
Other Titles Without metals or other endangered elements. Part 2