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Book Cover
E-book
Author Drzaic, Paul S

Title Liquid crystal dispersions / Paul S. Drzaic
Published Singapore ; River Edge, NJ : World Scientific, ©1995

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Description 1 online resource (xv, 429 pages) : illustrations (some color)
Series Series on liquid crystals ; v. 1
Series on liquid crystals ; v. 1.
Contents Preface -- Contents -- 1 INTRODUCTION -- The PDLC paradigm -- History -- Scope of the book -- References -- 2 RECIPES -- Polymer primer -- Polymer structure and physical properties -- Polymer chemistry -- Addition polymerization -- Step polymerization -- Ring-opening polymerization -- Emulsion methods for PDLC films -- Polyvinyl alcohol systems -- Latex-based systems -- Other water-based systems -- Phase separation methods for PDLC films -- Polymerization-induce phase separation (PIPS) -- Photoinitiated PIPS systems -- Thiol-ene systems
Acrylate systemsVariations in photocured PDLC systems -- Polymer network systems -- Thermally initiated PIPS systems -- Electron beam-initiated PIPS systems -- Thermally-induced phase separation (TIPS) -- Solvent-induced phase separation (SIPS) -- Other methods for PDLC formation -- Imbibing porous structures with liquid crystal -- Glass-dispersed systems -- Dispersed silica systems -- Mixtures of microspheres and liquid crystals -- Coatings, substrates, and film manufacture -- Aspects of film structure -- Film thickness -- Microscopy of PDLC films
Liquid crystal domain sizeMeasurement of droplet size -- Colloid sizing systems -- Measurement of droplet size using electron microscopy -- Light scattering -- Estimation from reorientation fields -- Analytic formulas for droplet size distributions -- Droplet size distributions -- Liquid crystal solubility in the polymer matrix -- Mass uptake -- Polymer refractive index -- Threshold for light scattering -- Calorimetry -- Electron microscopy -- Liquid Crystal/Polymer Phase Separation -- Phase diagrams for liquid crystal/monomer mixtures
Description of phase diagramsMeasurement of phase diagrams -- Phase separation in the binodal and spinodal regimes -- Calculation of phase diagrams -- Energetics and kinetics of PDLC film formation -- Phase separation kinetics -- References -- 3 NEMATIC CONFIGURATIONS WITHIN DROPLETS -- Factors controlling nematic alignment -- Theoretical considerations of droplet structures -- ALIGNMENT AND ELASTIC PROPERTIES OF LIQUID CRYSTALS -- Defect structures -- DEFECT STRUCTURES IN NEMATIC LIQUID CRYSTALS -- Analysis of director configurations -- Optical microscopy
Calculation of droplet patternsNuclear magnetic resonance -- Catalog of droplet structures -- Parallel wall alignment -- Bipolar configuration -- Concentric (aka toroidal or axial) structure -- Twisted bipolar -- Cholesteric droplets with parallel wall alignment -- Radial line defect (spherulite structure) -- Diametrical defect structure -- Double-radial defect -- Planar structures -- Escaped defect structures in cholesteric systems -- Focal conic textures -- Perpendicular anchoring -- Radial and twisted radial -- Axial (equatorial) -- Escaped radial
Summary Polymer-dispersed liquid crystal (PDLC) materials are of interest both for their potential in display technology and the fascinating science found in liquid crystals confined to small cavities. Liquid Crystal Dispersions is a comprehensive overview of the science and technology of this new class of materials. Topics covered include formation of PDLC devices, a catalog of droplet structures and transformations, device electro-optical properties, and applications. Liquid Crystal Dispersions will be of value to the nonspecialists keen on gaining an overview of this new field, as well as to specialists interested in a comprehensive review of work in this area
Bibliography Includes bibliographical references and index
Notes English
Print version record
Subject Polymer liquid crystals.
SCIENCE -- Energy.
SCIENCE -- Mechanics -- General.
SCIENCE -- Physics -- General.
Polymer liquid crystals
Dispersion
Flüssigkristall
Polymères cristaux liquides.
Form Electronic book
LC no. 96115358
ISBN 9789812831910
9812831916
1299280951
9781299280953