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E-book
Author Barrett, Jack.

Title Inorganic chemistry in aqueous solution / Jack Barrett
Published Cambridge : Royal Society of Chemistry, 2003

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Description 1 online resource (vii, 184 pages) : illustrations
Series Tutorial chemistry texts ; 21
Tutorial chemistry texts ; 21.
Contents 1. WATER AND ITS SOLVENT PROPERTIES. Introduction -- Liquid water -- 2. LIQUID WATER AND THE HYDRATION OF IONS. The structure of liquid water -- Ions and their hydration -- Gibbs energies and enthalpies of formation of hydrated ions -- Standard molar enthalpies of hydration of ions -- The absolute value for the standard molar enthalpy of hydration of the proton -- Absolute values of the standard molar enthalpies of hydration of ions -- Standard molar entropies of hydration of ions -- 3. ACIDS AND BASES; FORMS OF IONS IN AQUEOUS SOLUTION; ION HYDROLYSIS & COMPOUND SOLUBILITY. Acids and bases in aqueous solutions -- Brønsted and Lowry acids and bases -- pH and the pH scale -- Factors influencing acidic and basic behaviour in aqueous solutions -- Forms of ions in aqueous solution; hydrolysis -- Solubilities of ionic compounds in water -- 4. THERMODYNAMICS AND ELECTRODE POTENTIALS. Changes in standard Gibbs energy and their relation to standard electrode potentials -- The hydrated electron and absolute values of reduction potentials -- 5. THE STABILITIES OF IONS IN AQUEOUS SOLUTION. The limits of stability of ions in aqueous systems -- Latimer and Volt-equivalent (Frost) diagrams -- 6. PERIODICITY OF AQUEOUS CHEMISTRY I: S- AND P-BLOCK CHEMISTRY. Periodicity of the ions formed by the s- and p-block elements -- The detailed aqueous chemistry of the s- and p-block elements -- Summary of the s- and p-block periodicity -- 7. PERIODICITY OF AQUEOUS CHEMISTRY II: D-BLOCK CHEMISTRY. The ions formed by the transition elements -- Enthalpies of hydration of some transition element cations -- Variations in the enthalpies of hydration of the +2 and +3 ions of the transition elements -- Variations of ionic forms and redox behaviour across the first series of transition elements -- General redox chemistry of the d-block elements -- 8. PERIODICITY OF AQUEOUS CHEMISTRY III: F-BLOCK CHEMISTRY. The lanthanides -- The actinides -- Answers to problems -- Subject index
Summary This product is not available separately, it is only sold as part of a set. There are 750 products in the set and these are all sold as one entity. Inorganic Chemistry in Aqueous Solution reviews the chemistry of the elements in all their oxidation states in an aqueous environment. The nature of ions in solution is described in some detail and enthalpies and entropies of hydration of many ions are defined and recalculated from the best data available. These values are used to provide an understanding of the periodicities of standard reduction potentials. Standard reduction potential data for all of the elements, group-by-group, covering the s and p, d and f blocks of the Periodic Table is also included. Major sections are devoted to the acid/base behaviour and the solubilities of inorganic compounds in water. Inorganic Chemistry in Aqueous Solution is aimed at undergraduate chemistry students but will also be welcomed by geologists interested in this field. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples
Bibliography Includes bibliographical references and index
Notes English
Print version record
Subject Chemistry, Inorganic.
Solution (Chemistry)
Mineralogical chemistry.
inorganic chemistry.
solution.
Chemistry.
Science.
Mineralogical chemistry
Chemistry, Inorganic
Solution (Chemistry)
Form Electronic book
ISBN 9781847551139
1847551130
085404471X
9780854044719