| Description |
1 online resource (xiii, 256 pages) : illustrations |
| Contents |
Cover -- Contents -- Preface -- 1. Elementary -- 1.1 Rate of Reaction -- 1.1.1 Experimental Determination of Rate -- 1.2 Rate Constant -- 1.3 Order and Molecularity -- 1.4 Rate Equations -- 1.4.1 Integral Equations for n<sup>th</sup> Order Reaction of a Single Reactant -- 1.4.2 Integral Equations for Reactions Involving More than One Reactants -- 1.5 Half-life of a Reaction -- 1.6 Zero Order Reactions -- 1.7 First Order Reactions -- 1.8 Radioactive Decay as a First Order Phenomenon -- 1.9 Second Order Reactions -- 1.10 Third Order Reactions -- 1.11 Determination of Order of Reaction -- 1.11.1 Integration Method -- 1.11.2 Half-life Period Method -- 1.11.3 Graphical Method -- 1.11.4 Differential Method -- 1.11.5 Ostwald Isolation Method -- 1.12 Experimental Methods of Chemical Kinetics -- 1.12.1 Conductometric Method -- 1.12.2 Polarographic Technique -- 1.12.3 Potentiometric Method -- 1.12.4 Optical Methods -- 1.12.5 Refractometry -- 1.12.6 Spectrophotometry -- Exercises -- 2. Temperature Effect on Reaction Rate -- 2.1 Derivation of Arrhenius Equation -- 2.2 Experimental Determination of Energy of Activation and Arrhenius Factor -- 2.3 Potential Energy Surface -- 2.4 Significance of Energy of Activation Exercises -- Exercises -- 3. Complex Reactions -- 3.1 Reversible Reactions -- 3.1.1 Reversible Reaction When Both the Opposing Processes are Second Order -- 3.2 Parallel Reactions -- 3.2.1 Determination of Rate Constants -- 3.3 Consecutive Reactions -- 3.3.1 Concentration-Time Relation -- 3.4 Steady-State Treatment -- 3.5 Chain Reactions -- 3.5.1 Rate Determination -- 3.5.2 Reaction between H₂ and Br₂ -- 3.5.3 Chain Length -- 3.5.4 Chain Transfer Reactions -- 3.5.5 Branching Chain Explosions -- 3.5.6 Kinetics of Branching Chain Explosion -- 3.5.7 Free Radical Chains -- 3.5.8 Chain Length and Activation Energy in Chain Reactions -- Exercises -- 4. Theories of Reaction Rate -- 4.1 Equilibrium and Rate of Reaction -- 4.2 Partition Functions and Statistical Mechanics of Chemical Equilibrium -- 4.3 Partition Functions and Activated Complex -- 4.4 Collision Theory -- 4.4.1 Collision Frequency -- 4.4.2 Energy Factor -- 4.4.3 Orientation Factor -- 4.4.4 Rate of Reaction -- 4.4.5 Weakness of the Collision Theory -- 4.5 Transition State Theory -- 4.5.1 Thermodynamic Approach -- 4.5.2 Partition Function Approach -- 4.5.3 Comparison with Arrhenius Equation and Collision Theory -- 4.5.4 Explanation for Steric Factor in Terms of Partition Function -- 4.5.5 Reaction between Polyatomic Molecules -- 4.6 Unimolecular Reactions and the Collision Theory -- 4.6.1 Lindemann's Mechanism -- 4.6.2 Hinshelwood Treatment -- 4.6.3 Rice and Ramsperger, and Kassel (RRK) Treatment -- 4.6.4 Marcus Treatment -- 4.6.5 RRKM Theory -- 4.7 Kinetic and Thermodynamic Control -- 4.8 Hammond's Postulate -- 4.9 Prob |
| Summary |
Brings together facts and theories relating to the rates with which chemical reactions occur, from both the macroscopic and microscopic point of view. This book helps the reader achieve an understanding of the principles of chemical kinetics. It includes stereochemical discussions of reaction steps. It is useful for researchers and students |
| Analysis |
chemie |
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chemistry |
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fysische chemie |
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physical chemistry |
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katalyse |
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catalysis |
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Chemistry (General) |
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Chemie (algemeen) |
| Bibliography |
Includes bibliographical references (pages 247-249) and index |
| Notes |
Print version record |
| In |
Springer e-books |
| Subject |
Chemical kinetics.
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Chemical reactions.
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SCIENCE -- Chemistry -- Physical & Theoretical.
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Chimie.
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Science des matériaux.
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Chemical kinetics
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Chemical reactions
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Cinética química.
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Reações químicas.
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| Form |
Electronic book
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| ISBN |
9781402045479 |
|
1402045476 |
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1402045468 |
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9781402045462 |
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9786610852109 |
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6610852103 |
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