| Description |
1 online resource (611 p.) |
| Series |
The ECS Series of Texts and Monographs |
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The ECS Series of Texts and Monographs
|
| Contents |
Cover -- Title Page -- Copyright -- Contents -- Preface to the Fourth Edition -- Preface to the Third Edition -- Preface to the Second Edition -- Preface to the First Edition -- Chapter 1 INTRODUCTION -- 1.1 Definitions -- 1.2 Thermodynamics and Potential -- 1.3 Kinetics and Rates of Reaction -- 1.4 Transport -- 1.5 Concentration Overpotential and the Diffusion Potential -- 1.6 Overall Cell Potential -- Chapter 2 THERMODYNAMICS IN TERMS OF ELECTROCHEMICAL POTENTIALS -- 2.1 Phase Equilibrium -- 2.2 Chemical Potential and Electrochemical Potential |
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2.3 Definition of Some Thermodynamic Functions -- 2.4 Cell with Solution of Uniform Concentration -- 2.5 Transport Processes in Junction Regions -- 2.6 Cell with a Single Electrolyte of Varying Concentration -- 2.7 Cell with Two Electrolytes, One of Nearly Uniform Concentration -- 2.8 Cell with Two Electrolytes, Both of Varying Concentration -- 2.9 Lithium-Lithium Cell With Two Polymer Electrolytes -- 2.10 Standard Cell Potential and Activity Coefficients -- 2.11 Pressure Dependence of Activity Coefficients -- 2.12 Temperature Dependence of Cell Potentials -- References |
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Chapter 3 THE ELECTRIC POTENTIAL -- 3.1 The Electrostatic Potential -- 3.2 Intermolecular Forces -- 3.3 Outer and Inner Potentials -- 3.4 Potentials of Reference Electrodes -- 3.5 The Electric Potential in Thermodynamics -- References -- Chapter 4 ACTIVITY COEFFICIENTS -- 4.1 Ionic Distributions in Dilute Solutions -- 4.2 Electrical Contribution to the Free Energy -- 4.3 Shortcomings of the Debye-Hückel Model -- 4.4 Binary Solutions -- 4.5 Multicomponent Solutions -- 4.6 Measurement of Activity Coefficients -- 4.7 Weak Electrolytes -- References -- Chapter 5 REFERENCE ELECTRODES |
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5.1 Criteria for Reference Electrodes -- 5.2 Experimental Factors Affecting Selection of Reference Electrodes -- 5.3 The Hydrogen Electrode -- 5.4 The Calomel Electrode and Other Mercury-Mercurous Salt Electrodes -- 5.5 The Mercury-Mercuric Oxide Electrode -- 5.6 Silver-Silver Halide Electrodes -- 5.7 Potentials Relative to a Given Reference Electrode -- References -- Chapter 6 POTENTIALS OF CELLS WITH JUNCTIONS -- 6.1 Nernst Equation -- 6.2 Types of Liquid Junctions -- 6.3 Formulas for Liquid-Junction Potentials -- 6.4 Determination of Concentration Profiles -- 6.5 Numerical Results |
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6.6 Cells with Liquid Junction -- 6.7 Error in the Nernst Equation -- 6.8 Potentials Across Membranes -- 6.9 Charged Membranes Immersed in an Electrolytic Solution -- References -- Chapter 7 STRUCTURE OF THE ELECTRIC DOUBLE LAYER -- 7.1 Qualitative Description of Double Layers -- 7.2 Gibbs Adsorption Isotherm -- 7.3 The Lippmann Equation -- 7.4 The Diffuse Part of the Double Layer -- 7.5 Capacity of the Double Layer in the Absence of Specific Adsorption -- 7.6 Specific Adsorption at an Electrode-Solution Interface -- References -- Chapter 8 ELECTRODE KINETICS |
| Notes |
Description based upon print version of record |
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8.1 Heterogeneous Electrode Reactions |
| Form |
Electronic book
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| Author |
Balsara, Nitash P
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| ISBN |
9781119514596 |
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1119514592 |
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