| Description |
1 online resource (350 p.) |
| Contents |
1.6: Mechanism of Absorption and Emission -- 1.7: Transition Probability and Selection Rule -- 1.7.1: Transition Moment and Transition Moment Integral -- 1.7.2: Electronic Selection Rules -- 1.7.3: Vibrational Selection Rules -- 1.7.4: Rotational Selection Rules -- 1.8: Line Width and Line Shapes -- 1.8.1: Spectral Line Broadening and Line Shapes -- 1.8.2: Local Effects Broadening -- 1.8.3: Natural Line Broadening -- 1.8.4: Doppler Broadening -- 1.8.5: Pressure (Collision Broadening) -- 1.8.6: Broadening due to Inhomogeneous Local Effects -- 1.8.7: Broadening due to Non-local Effects |
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1.9: Fourier Transform -- Chapter 2: Nuclear Magnetic Resonance Spectroscopy -- 2.1: Introduction -- 2.2: Nature of Spinning Nucleus -- 2.3: Effect on the Nucleus of an External Magnetic Field -- 2.4: Precessional Motion of Nucleus -- 2.5: Precessional Frequency: Larmor Frequency -- 2.6: Energy Transitions and the Origin of NMR -- 2.7: Theory of NMR -- 2.7.1: Nuclear Spin and Magnetic Moment and Interaction Between Nuclear Spin and Magnetic Field -- 2.7.2: Population of Nuclear Energy Levels -- 2.7.3: Saturation and Relaxation -- 2.8: Concept of Chemical Shift -- 2.9: Types of Shielding |
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2.10: Factors Affecting Chemical Shift -- 2.10.1: Effect of Electronegativity (Inductive Effect) -- 2.10.2: Van der Waal's Deshielding -- 2.10.3: Magnetic Anisotropy -- 2.10.3.1: Alkenes -- 2.10.3.2: Alkynes -- 2.10.3.3: Carbonyl compounds -- 2.10.3.4: Aromatic compounds -- 2.10.3.5: Effect of hydrogen bonding -- 2.10.3.6: Effect of solvents (types, concentration, temperature, and hydrogen bonding) -- 2.10.3.7: Solvents used in NMR -- 2.11: Spin-Spin Coupling -- 2.11.1: The Splitting of Signals in Proton NMR Spectra -- 2.11.2: Theory of Spin-Spin Coupling |
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2.12: The General Rule of Spin-Spin Splitting: The (n + 1) Splitting Rule -- 2.13: Complex NMR Spectra: Breakdown of (n + 1) Splitting Rule -- 2.13.1: Multiplicative Splitting -- 2.13.2: Non-first-order Spectra: Breakdown of the (n + 1) Rule -- 2.14: The Coupling Constant (J) -- 2.14.1: Factors Influencing Coupling Constant, J, and Various Types of Couplings -- 2.14.1.1: Geminal coupling -- 2.14.1.2: Vicinal coupling -- 2.14.1.3: Long-range proton-proton coupling -- 2.14.1.4: Heteronuclear coupling -- 2.14.1.5: 1H-13C spin-spin coupling -- 2.14.1.6: Deuterium coupling |
| Notes |
Description based upon print version of record |
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2.15: Proton Exchange Reaction in NMR Spectrum of Alcohol |
| Form |
Electronic book
|
| Author |
Das, S. S
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Singh, N. B
|
| ISBN |
9781000910933 |
|
1000910938 |
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