| Description |
1 online resource (158 pages) : illustrations |
| Contents |
SELECTIVE CATALYTICHYDROCARBONS OXIDATION:NEW PERSPECTIVES; CONTENTS; PREFACE; INTRODUCTION; HOMOGENEOUS CATALYTIC OXIDATIONS OFALKYLARENS WITH MOLECULAR OXYGEN; METHODS FOR ENHANCING THE ACTIVITYAND SELECTIVITY OF HOMOGENEOUSCATALYSTS IN THE OXIDATION PROCESSES; III. 1. IMMOBILIZATION OF HOMOGENEOUS CATALYST ONHETEROGENEOUS SUPPORT FOR INCREASE IN ACTIVITYAND SELECTIVITY OF CATALYST IN THE ALKYLARENSOXIDATIONS; III. 2. MODIFICATION OF METALLOCOMPLEX CATALYSTSBY ADDITION OF MONODENTATE AXIAL LIGANDS; Scheme III. 2.1.; Scheme III. 2.2.; Scheme III. 2.3.; Scheme III. 2.4 |
|
Introduction of Activating Additives in the Course of Catalyzed OxidationProcessIII. 3. MODELING OF TRANSITION METAL COMPLEXCATALYSTS UPON ADDITION OF AMMONIUM QUATERNARYSALTS AND MACRO-CYCLE POLYETHERS AS LIGANDSMODIFIERS. THE ROLE OF HYDROGEN-BONDINGINTERACTIONS; Catalysis by Ni(L1)2 in the Presence of Ligand-modifiers L2; Scheme III. 3.1.; Catalysis by Fe(III)(acac)3 in the Presence of Ligand-modifiers L2; Catalysis by Co(II)(acac)2 in the Presence of Ligand-modifiers L2; Scheme III. 3.2 |
|
III. 4. TRIPLE CATALYTIC SYSTEMS INCLUDING BIS(ACETYLACETONATE) NI(II) AND ADDITIVES OF ELECTRONDONORCOMPOUND L2 AND PHENOL AS EXO LIGANDSTHE ROLE OF HYDROGEN-BONDINGINTERACTIONS IN MECHANISMS OFHOMOGENOUS CATALYSIS; IV. 1. THE EFFECT OF SMALL AMOUNTS OF H2O IN THEETHYLBENZENE OXIDATION, CATALYZED WITH{FE(III)(ACAC)3+R4NBR} SYSTEM; IV. 2. THE EFFECT OF SMALL AMOUNTS OF H2O IN THEETHYLBENZENE OXIDATION, CATALYZED WITH{FE(III)(ACAC)3+18C6} SYSTEM; THE MECHANISM OF HYDROCARBON LIQUIDPHASE OXIDATION WITH DIOXYGEN, CATALYZED BY COMPLEXES OF TRANSITIONMETALS |
|
VI. 2. CATALYSIS WITH COBALT COMPLEXESVI. 3. CATALYSIS WITH COMPLEXES OF NI- AND CO SALTSWITH 18C6 AND 15C5; VI. 4. CATALYSIS WITH NICKEL COMPLEXES, ACTIVATED BYADDITIVES OF MONODENTATE LIGANDS; VI. 5. CATALYSIS WITH IRON COMPLEXES; CATALYTIC OXIDATION OF TOLUENE ANDCUMENE IN HYDROPEROXIDES IN PRESENCEOF SYSTEM {NI(L1)2 + L2}; VII. 1. TOLUENE OXIDATION, CATALYZED WITH SYSTEM{NI(II)(ACAC)2 + MP}; Scheme VII. 1.1.; Scheme VII. 1.2.; VII. 2. OXIDATION OF CUMENE, CATALYZED WITH SYSTEM{NI(II)(ACAC)2 + MP}; SELF-ASSEMBLY AND SELF-ORGANIZEDSTRUCTURES, MEDIATED BYTRANSITION METALS; CONCLUSION; REFERENCES |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record |
| Subject |
Hydrocarbons -- Oxidation
|
|
Catalytic cracking.
|
|
Transition metal complexes.
|
|
Catalysis.
|
|
Catalysis
|
|
TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
|
|
SCIENCE -- Chemistry -- Industrial & Technical.
|
|
Catalysis
|
|
Catalytic cracking
|
|
Hydrocarbons -- Oxidation
|
|
Transition metal complexes
|
| Form |
Electronic book
|
| Author |
Mosolova, Larisa A
|
|
Zaikov, Gennadiĭ Efremovich
|
| ISBN |
9781612093697 |
|
1612093698 |
|
