| Description |
1 online resource (331 p.) |
| Contents |
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Photocatalytic Hydrogen Production in the Context of Sustainable Energy -- 1.1 The Transition to Sustainable Energy -- 1.1.1 Trends in Primary Energy Production -- 1.1.2 Fossil Reserves -- 1.1.3 Carbon Dioxide Emissions and Global Warming -- 1.1.4 Strategic Low-carbon Goals and Energy Sustainability -- 1.2 Hydrogen as Renewable Energy Carrier -- 1.2.1 The Colors of Hydrogen: Toward Clean Hydrogen -- 1.2.2 Costs of Hydrogen Production -- 1.2.3 Solar Fuels and Synthetic Fuels -- 1.3 The Opportunity for Photocatalytic Hydrogen |
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1.3.1 Photoelectrocatalytic Water Splitting -- 1.3.2 Photocatalytic Water Splitting -- 1.3.3 Photocatalytic Hydrogen from Various Feedstocks by Photoreforming -- 1.3.4 Photobiocatalytic Hydrogen -- 1.4 Outlook -- Acknowledgments -- References -- Chapter 2 Fundamentals and Concepts of Photocatalytic Hydrogen Evolution -- 2.1 Heterogeneous Photocatalysis -- 2.2 Thermodynamic Description -- 2.3 Standard Electrode Potential -- 2.4 Photocatalysts for Hydrogen Evolution -- 2.5 Co-catalysts for Hydrogen Evolution -- 2.6 Role of Platinum -- 2.7 Anatase and Rutile |
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2.8 Outlooks on Photocatalytic Hydrogen Evolution -- References -- Chapter 3 Isotopic Substitution to Unravel the Mechanisms of Photocatalytic Hydrogen Production -- 3.1 Introduction -- 3.2 Isotopic Substitution on the Solvent or Substrate -- 3.2.1 Water -- 3.2.2 Alcohols -- 3.2.3 Carbonyl Compounds -- 3.2.4 Aromatic Compounds -- 3.3 Isotopic Substitution on the Photocatalyst -- 3.3.1 Ti Substitution -- 3.3.2 O Substitution -- 3.3.3 H Substitution -- 3.3.4 Substitution in Materials Other than TiO2 -- 3.4 Concluding Remarks -- Acknowledgments -- References |
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Chapter 4 Photocatalytic Overall Water Splitting and Related Processes for Strategic Energy Storage into Hydrogen -- 4.1 Photocatalysis as a Water Splitting Technology Option -- 4.1.1 What Is (and What Is Not) Photocatalytic Overall Water Splitting? -- 4.1.2 Comparison to Competing Technologies: Photoelectrochemical and Photovoltaic-Electrochemical -- 4.2 Basics and Fundamentals of Photocatalytic Water Splitting -- 4.2.1 Water Splitting Thermodynamics, Energy Balance and Metrics -- 4.2.2 Photophysics of Heterogeneous Semiconductor Photocatalysts |
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4.2.3 The Challenging Kinetics of Water Splitting and Co-Catalyst Requirements -- 4.2.4 Photoreactor Engineering and Process Conditions -- 4.3 Materials for Photocatalytic Overall Splitting of Pure Water into H2 and O2 -- 4.3.1 Single Light Absorber Configuration Based on Metal Oxide Semiconductors -- 4.3.2 Doped Metal Oxides Improve Single Absorber Photocatalysts -- 4.3.3 Modifications of Single Light Absorber Photocatalysts: (Oxy)nitrides, (Oxy)sulfides -- 4.3.4 Organic or Metal-Organic Semiconductors for Photocatalytic Water Splitting |
| Notes |
Description based upon print version of record |
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4.3.5 Bioinspired Two-Absorber Z-Scheme Configurations toward Artificial Chloroplasts |
| Form |
Electronic book
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| ISBN |
9783527835416 |
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3527835415 |
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