Cover ; Half Title ; Title Page ; Copyright Page ; Contents ; Preface ; Authors ; Abbreviations ; Chapter 1: Basic Principles of EPR and NMR Spectroscopy ; 1.1 Electron and Nuclear Magnetic Moments in the Magnetic Field ; 1.2 Instrumentation for CW EPR Spectroscopy
1.3 Main Parameters Characterizing EPR Spectra 1.4 EPR Spectra of Frozen Solutions ; 1.5 Instrumentation for Pulsed FT NMR Spectroscopy ; 1.6 Main Characteristics of NMR Spectra ; 1.6.1 Chemical Shift ; 1.6.2 Spin-Spin Coupling ; 1.6.3 NMR Line Width ; 1.7 Bloch Equations
1.8 Pulsed FT NMR Spectroscopy References ; Chapter 2: Some NMR Spectroscopic Techniques Used in Homogeneous Catalysis ; 2.1 Measuring 1H and 13C NMR Spectra of a Sample Compound ; 2.1.1 One- and Two-Dimensional 1H and 13C NMR Spectra ; 2.1.2 1H COSY versus 1H TOCSY Spectra
2.2 1H Spectra of Paramagnetic Molecules 2.2.1 Probing the Structure of an Unknown Ni(II) Complex by Multinuclear NMR ; 2.2.2 Temperature Dependence of the Paramagnetic Shift ; 2.2.2.1 Temperature Dependence of the Paramagnetic Shift of Monomeric Compounds
2.2.2.2 Temperature Dependence of Paramagnetic Shift of Antiferromagnetic Dimers 2.2.2.3 Measuring Magnetic Susceptibility (Evans Method) for Studying Spin Equilibrium ; References
Summary
This book reviews advances in important and practically relevant homogeneous catalytic transformations, such as single-site olefin polymerizations and chemo- and stereo-selective oxidations. Close attention is paid to the experimental investigation of the active sites of catalytic oxidation systems and their mechanisms. Major subjects include the applications of NMR and EPR spectroscopic techniques and data obtained by other physical methods. The book addresses a broad readership and focus on widespread techniques available in labs with NMR and EPR spectrometers
Bibliography
Includes bibliographical references and index
Notes
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