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Title MWW-Type titanosilicate : synthesis, structural modification and catalytic applications to green oxidations / Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
Published Heidelberg : Springer, 2013
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Description 1 online resource (viii, 125 pages) : illustrations
Series SpringerBriefs in molecular science, Green chemistry for sustainability, 2191-5407
SpringerBriefs in molecular science. Green chemistry for sustainability. 2191-5407
Contents Introduction -- Synthesis of Ti-MWW Zeolite -- Structural Modification of Ti-MWW: A Door to Diversity -- Catalytic Properties of Ti-MWW in Selective Oxidation Reactions -- Conclusions and Prospects
Summary This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta
Bibliography Includes bibliographical references
Notes Online resource; title from PDF title page (SpringerLink, viewed August 20, 2013)
Subject Zeolites.
Silicates.
Green chemistry.
Form Electronic book
Author Wu, Peng, author
LC no. 2013945287
ISBN 3642391141
364239115X (electronic bk.)
9783642391149
9783642391156 (electronic bk.)