| Description |
1 online resource |
| Contents |
Of Part B -- 1. Alkylation of Carbon via Enolates and Enamines -- 1.1. Generation of Carbon Nucleophiles by Proton Abstraction -- 1.2. Kinetic Versus Thermodynamic Control in Formation of Enolates -- 1.3. Other Means of Generating Enolates -- 1.4. Alkylations of Enolates -- 1.5. Generation and Alkylation of Dianions -- 1.6. Solvent Effects in Enolate Alkylations -- 1.7. Oxygen Versus Carbon as the Site of Alkylation -- 1.8. Alkylations of Aldehydes, Esters, Nitriles, and Nitro Compounds -- 1.9. The Nitrogen Analogs of Enols and Enolates -- Enamine Alkylations -- 1.10. Alkylation of Carbon by Conjugate Addition -- General References -- Problems -- 2. Reactions of Nucleophilic Carbon Species with Carbonyl Groups -- 2.1. Aldol Condensation -- 2.2. Related Condensation Reactions -- 2.3. The Mannich Reaction -- 2.4. Acylation of Nucleophilic Carbon -- 2.5. The Wittig Reaction -- 2.6. Sulfur Ylides as Nucleophiles -- 2.7. Nucleophilic Addition-Cyclization -- General References -- Problems -- 3. Addition Reactions of Carbon-Carbon Multiple Bonds -- 3.1. Addition of Hydrogen -- 3.2. Addition of Hydrogen Halides -- 3.3. Hydration and Other Acid-Catalyzed Additions -- 3.4. Oxymercuration -- 3.5. Addition of Halogens to Olefins -- 3.6. Addition of Other Electrophilic Reagents -- 3.7. Electrophilic Substitution Alpha to Carbonyl Groups -- 3.8. Hydroboration -- 3.9. Additions to Allenes and Alkynes -- General References -- Problems -- 4. Reduction of Carbonyl and Other Functional Groups -- 4.1. Hydride-Transfer Reagents -- 4.2. Hydrogen-Atom Donors -- 4.3. Dissolving-Metal Reductions -- General References -- Problems -- 5. Organometallic Compounds -- 5.1. Organic Derivatives of Group I and II Metals -- 5.2. Organic Derivatives of Group IIb Metals -- 5.3. Organic Derivatives of Transition Metals -- 5.4. Catalysis of Rearrangements by Metal Ions and Complexes -- 5.5. Organometallic Compounds with?-Bonding -- General References -- Problems -- 6. Cycloadditions and Unimolecular Rearrangements and Eliminations -- 6.1. Cycloaddition Reactions -- 6.2. Photochemical Cycloadditions -- 6.3. SigmatropicRearrangements -- 6.4. Unimolecular Thermal Elimination Reactions -- General References -- Problems -- 7. Aromatic Substitution Reactions -- 7.1. Electrophilic Aromatic Substitution -- 7.2. Nucleophilic Aromatic Substitution -- 7.3. Substitutions Involving Aryl Free Radicals -- 7.4. Reactivity of Polycyclic Aromatics -- General References -- Problems -- 8. Reactions Involving Carbenes, Nitrenes, and Other Electron-Deficient Intermediates -- 8.1. Carbenes -- 8.2. Nitrenes -- 8.3. Rearrangements of Electron-Deficient Intermediates -- 8.4. Fragmentation Reactions -- 8.5. Some Synthetically Useful Carbonium-Ion Reactions -- General References -- Problems -- 9. Oxidations -- 9.1. Oxidation of Alcohols to Aldehydes, Ketones, or Carboxylic Acids -- 9.2. Addition of Oxygen at Carbon-Carbon Double Bonds -- 9.3. Cleavage of Carbon-Carbon Double Bonds -- 9.4. Selective Oxidative Cleavages at Other Functional Groups -- 9.5. Oxidations of Ketones and Aldehydes -- 9.6. Allylic Oxidation of Olefins -- 9.7. Oxidations at Unfunctionalized Carbon Atoms -- General References -- Problems -- 10. Multistep Syntheses -- 10.1. Protective Groups -- 10.2. Synthetic Equivalent Groups -- 10.3. Asymmetric Syntheses -- 10.4. Synthetic Strategy -- General References -- Problems -- 11. Synthesis of Macromolecules -- 11.1. Polymerization -- 11.2. Peptide and Protein Synthesis -- 11.3. Nucleosides, Nucleotides, and Polynucleotides -- General References -- Problems -- References for Problems |
| Subject |
Chemistry.
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Chemistry, Organic.
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chemistry.
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organic chemistry.
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Chemistry.
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Chemistry, Organic.
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| Form |
Electronic book
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| ISBN |
9780306473807 |
|
0306473801 |
|
9780387714813 |
|
0387714812 |
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