| Description |
1 online resource |
| Contents |
Intro; Title page; Table of Contents; Copyright; Dedication; Contributors; Foreword; Preface; Part 1: History and State of the Art of the "Direct Synthesis" Methods; Educational and Historical Aspects of Direct Synthesis of Metal Complexes; Abstract; 1 Introduction; 2 Historical Development of Direct Synthesis; 3 Pedagogical Value: Why Incorporate Direct Synthesis in the Undergraduate Laboratory?; 4 Ultrasonic and Microwave Mediated Direct Synthesis; 5 Conclusion; Recent Advances in Direct Synthesis of Organometallic and Coordination Compounds; Abstract; Acknowledgment; 1 Indirect Synthesis |
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2 Direct Synthesis3 Group I; 4 Group 7; 5 Group 8; 6 Group 9; 7 Group 10; 8 Group 11; 9 Group 12; 10 Group 13; 11 Group 14; 12 Group 15; 13 Group 16; 14 Summary and Outlook; Direct Electrochemical Synthesis of Metal Complexes; Abstract; 1 Basic Concepts; 2 Electrochemical Thermodynamics; 3 Electrochemical Kinetics; 4 Reaction Mechanisms; 5 Electrochemical Cells; 6 Solvents and Supporting Electrolytes; 7 Metals; 8 Ligands; 9 Conclusions and Further Outlook; Cryochemical Co-condensation of Metal Vapors and Organic Compounds; Abstract; 1 Introduction |
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2 Formation of Metal Organosols Under the Low-temperature Vapor Co-condensation3 Preparation of Metal-Organic Compounds via the Metal-Vapor Cryosynthesis; 4 Synthesis of Catalysts by Low-temperature Co-condensation of Metal Vapors and Organic Compounds; 5 Conclusions; Part 2: "Direct" Methods in the Preparation of Distinct Types of Complexes; Direct Synthesis of Heterometallic Complexes; Abstract; 1 Introduction; 2 Salt Route; 3 Ammonium Salt Route; 4 Conclusions; New Trends in the Direct Synthesis of Phthalocyanine/Porphyrin Complexes; Abstract; Acknowledgments; 1 Introduction |
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2 Classical Approach of Phthalocyanine/Porphyrin Complexes Direct Synthesis3 New Methods of Phthalocyanine/Porphyrin Complexes Direct Synthesis; Increasing the Rate of the Direct Synthesis Complex Compounds; Abstract; 1 The Accumulation of Metallic Elements in the Technological Waste; 2 The Use of Direct Synthesis of Complex Compounds for Extraction of Metallic Elements from Industrial Waste; 3 Effect on the Rate, Selectivity, and Yield of the Donor-Acceptor Interaction Product of a Number of Physical and Chemical Factors |
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4 Accelerate the Direct Synthesis of Complex Compounds When Moving and Delivery of the Ligand Molecule in the Surfactant Micelles5 Effect of Porous Silica on Coordinating the Interaction; 6 Contact the Kinetic Characteristics of the Direct Synthesis of Complex Connections with the Debye Temperature of the Metal and Coefficient Grüneisen; Part 3: "Direct Synthesis" and Nanotechnology; Direct Synthesis of Nanomaterials: Building Bridges Between Metal Complexes and Nanomaterials; Abstract; 1 Introduction; 2 Analogies Among Metal Complexes and Nanomaterials; 3 Direct Synthesis of Nanomaterials |
| Summary |
"Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and moreDescribes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and waterIncludes experimental procedures, with examples of direct synthesis, at the end of each chapter"-- Provided by publisher |
| Notes |
Includes index |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Online resource; title from PDF title page (EBSCO, viewed April 26, 2018) |
| Subject |
Coordination compounds -- Synthesis
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Organometallic compounds -- Synthesis
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SCIENCE -- Chemistry -- Organic.
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Coordination compounds -- Synthesis
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Organometallic compounds -- Synthesis
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| Form |
Electronic book
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| LC no. |
2020304494 |
| ISBN |
9780128110621 |
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0128110627 |
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