| Description |
1 online resource (xix, 439 pages) : illustrations (some color) |
| Contents |
Title Page ; Copyright Page; Contents; About the Editors; List of Contributors; Foreword ; Preface; Part I Fundamentals ; Chapter 1 Graphite Oxide Story -- From the Beginning Till the Graphene Hype; 1.1 Introduction; 1.2 Preparation of Graphite Oxide; 1.2.1 Trials for Improving and Simplifying GO Preparation; 1.2.2 Over-Oxidation of Graphite ; 1.2.3 Formation Mechanism -- First Approximation; 1.3 Discovery of Essential Functional O-Containing Groups and its Relation to the Development of Structural Models; 1.3.1 Analytical Composition of Graphite Oxide |
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1.3.2 Creation of the Structural Model from 1930 till 20061.3.3 Considerations for the Formation Mechanism -- Second Approximation; 1.4 Properties of Graphite Oxide; 1.4.1 Thermal Degradation and its Products; 1.4.2 Chemical Reduction Reactions; 1.4.3 Reactions with Acids and Bases; 1.4.4 "Osmotic Swelling": Hydration Behavior and Colloid Formation; 1.4.5 GO Acidity; 1.4.6 Intercalation and Functionalization Reactions; 1.4.7 Functional Groups, their Reactions and their Relation to GO Formation and Destruction; 1.5 Epilogue; References |
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Chapter 2 Mechanism of Formation and Chemical Structure of Graphene Oxide2.1 Introduction; 2.2 Basic Concepts of Structure; 2.3 Preparation Methods; 2.4 Mechanism of Formation; 2.4.1 Theoretical Studies and System Complexity; 2.4.2 Step 1: Formation of Stage-1 H2SO4-GIC Graphite Intercalation Compound; 2.4.3 Step 2: Transformation of Stage-1 H2SO4-GIC to Pristine Graphite Oxide; 2.4.4 Pristine Graphite Oxide Structure; 2.4.5 Step 3: Delamination of Pristine Graphite Oxide; 2.5 Transformation of Pristine Graphite Oxide Chemical Structure Upon Exposure to Water |
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2.6 Chemical Structure and Origin of Acidity2.6.1 Structural Models and the Actual Structure; 2.6.2 Origin of Acidity and the Dynamic Structural Model; 2.7 Density of Defects and Introduction of Oxo-Functionalized Graphene; 2.7.1 Oxo-Functionalized Graphene by Charpy-Hummers Approach ; 2.7.2 Oxo-Functionalized Graphene from Graphite Sulfate ; 2.8 Addressing the Challenges of the Two-Component Structural Model; 2.9 Structure of Bulk Graphite Oxide; 2.10 Concluding Remarks; References; Chapter 3 Characterization Techniques; 3.1 Nuclear Magnetic Resonance Spectroscopy of Graphene Oxide |
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3.1.1 Nuclear Magnetic Resonance Spectroscopy in Solids3.1.2 Nuclear Magnetic Resonance Spectroscopy of Graphene Oxide; 3.1.3 Discussion; 3.2 Infrared Spectroscopy; 3.3 X-ray Photoelectron Spectroscopy ; 3.4 Raman Spectroscopy; 3.4.1 Introduction; 3.4.2 Raman Spectroscopy on Molecules; 3.4.3 Raman Spectroscopy on Graphene, GO and RGO; 3.4.4 Defects in Graphene; 3.4.5 Raman Spectra of GO and RGO; 3.4.6 Statistical Raman Microscopy (SRM); 3.4.7 Outlook; 3.5 Microscopy Methods; 3.5.1 Scanning Electron Microscopy; 3.5.2 Atomic Force Microscopy; 3.5.3 Transmission Electron Microscopy |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record |
| Subject |
Graphene.
|
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Graphene -- Oxidation
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Graphene -- Industrial applications
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TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
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Graphene
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| Form |
Electronic book
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| Author |
Dimiev, Ayrat M., 1965-
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Eigler, Siegfried, 1978-
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| ISBN |
9781119069447 |
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1119069440 |
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9781119069430 |
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1119069432 |
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