| Description |
1 online resource (xvii, 535 pages) : illustrations (some color) |
| Contents |
Front Cover; Encapsulated Catalysts; Copyright; Dedication; Contents; Contributors; About the Authors; Chapter 1: Organically Encapsulated Polyoxometalate Catalysts: Supramolecular Composition and Synergistic Catalysis; 1. Introduction of Polyoxometalates; 2. POMs as Inorganic Polyanionic Cluster Catalysts; 3. Encapsulations of Inorganic Clusters; 4. Catalysis of Encapsulated POM Complexes in Solution; 5. Catalysis of Encapsulated POM Complexes in Self-Assemblies; 6. Catalysis of Encapsulated POMs Complexes at Solution Interface; 7. Catalysis of Encapsulated POMs Complexes in Solid Matrix |
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8. ConclusionReferences; Chapter 2: Encapsulation of Polyoxometalate Catalysts Into Dendrimers: One Step in Making Stable and Recoverable Homogene ... ; 1. Introduction; 2. DENDRI-POM Hybrids in Which POM Units Are Encapsulated Into the Dendrimers; 2.1. Achiral DENDRI-POM Hybrids; 2.1.1. DENDRI-POMs With POM Units Encapsulated Into the Cavities of Dendrimers; Synthesis of 36-Armed Dendrimers Bearing 6-Internal Amino Groups:; Encapsulation of POM Units Into 36-Armed Dendrimers:; Catalytic Evaluation of 36-Armed DENDRI-POM Hybrid 4b in the Oxidation Reaction |
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2.1.2. Polyoxometalate With a Single POM Anion Encapsulated Into the Dendritic CorePreparation of Allyl and n-Propyl-Terminated Dendritic Structures Able to Encapsulate POM Anions:; DENDRI-POM Hybrids Based on the Venturello Polyanion:; DENDRI-POMs Bearing Epoxy, n-Propyl and Aryl Sulfide Peripheral Groups:; POM-Cored Dendrimers Based on 1,1'-Binaphthyl-2-Methylpyridine Ligand; Preparation of 1,1'-Binaphthyl-2-Methylpyridine-Based DENDRI-POMs:; Evaluation of 1,1'-Binaphthyl-2-Methylpyridine DENDRI-POMs in Oxidation Reactions |
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DENDRI-POM Hybrids Based on Polyanions Other Than the Venturello Species:DENDRI-POM Hybrids Based on Zirconium-Peroxotungstosilicate Anion:; DENDRI-POM Hybrids Based on Keggin, Dawson, and Preyssler Anions:; 2.2. Optically Active POM-Encapsulated Dendrimers; 2.2.1. Optically Active DENDRI-POM Hybrids Based on 1-Phenylethylamine; Enantiopure DENDRI-POM Hybrids Prepared From Monopodal Dendrons:; Circular Dichroïsm (CD) Experiments of DENDRI-POM Hybrids:; Vibrational Absorption and Circular Dichroïsm (CVD) Analyses of DENDRI-POMs:; Electronic Absorption and Emission of DENDRI-POM Hybrids |
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Evaluation of Enantiopure DENDRI-POM Hybrids in an Oxidation Reaction:Enantiopure Tripodal DENDRI-POM Hybrids:; Circular Dichroïsm (CD) Experiments of DENDRI-POM Hybrids:; Vibrational Absorption and Circular Dichroïsm (CVD) Analyses:; Electronic Absorption and Emission Studies:; Oxidation Catalysis With Enantiopure Tripodal DENDRI-POM Hybrids:; Catalyst Recovery and Reuse of Enantiopure DENDRI-POM Catalysts:; 2.2.2. l-Proline-Derived DENDRI-POM Hybrids; Evaluation of l-Proline-Derived DENDRI-POMs in Oxidation Reactions |
| Summary |
Encapsulated Catalysts provides valuable information for chemists, chemical engineers, and materials scientists in this promising area. The book describes many kinds of encapsulated catalysts and their applications in chemistry, including organic, inorganic, hybrid, and biological systems. Unlike other works, which discuss traditional supports, this useful resource uniquely focuses on extremely important topics, such as the encapsulation effects on reactivity and selectivity, the difficulty of their separation from reaction mixture, and/or their sensitivity to reaction conditions, and the limit of their industrial applications. In addition, the book covers the immobilization of homogenous catalysts on inorganic or organic supports and how it enables the separation of homogenous catalysts, as well as the protection or reuse of catalysts |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Vendor-supplied metadata |
| Subject |
Catalysts.
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Polyoxometalates.
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Nanoparticles.
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catalyst.
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SCIENCE -- Chemistry -- Physical & Theoretical.
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Catalysts
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Nanoparticles
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Polyoxometalates
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| Form |
Electronic book
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| Author |
Sadjadi, Samahe, editor
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| ISBN |
9780128039052 |
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0128039051 |
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