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Book Cover
E-book
Author Lazzari, Luciano, 1948-

Title Engineering tools for corrosion : design and diagnosis / Luciano Lazzari
Published Duxford : Elsevier Science, 2017

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Description 1 online resource (190 pages)
Series European Federation of Corrosion (EFC) series ; no. 68
Publications (European Federation of Corrosion) ; no. 68.
European Federation of Corrosion (EFC) Series
Contents 880-01 Front Cover; Engineering Tools for Corrosion; Copyright Page; Dedication; Contents; Author Biography; List of Symbols and Abbreviations; Units; Premise; Volumes in the EFC Series List; 1 Basic Principles; 1.1 Corrosion reactions; 1.2 Electrochemical mechanism; 1.2.1 Anodic processes; 1.2.2 Cathodic processes; 1.3 Stoichiometry (Faraday Law); 1.4 Thermodynamic conditions; 1.4.1 Reference electrodes; 1.4.2 Potential of anodic reaction, Ea; 1.4.3 Potential of cathodic reaction, Ec; 1.4.3.1 Hydrogen evolution; 1.4.3.2 Oxygen reduction; 1.5 Kinetics of aqueous corrosion; 1.5.1 Anodic overvoltage
880-01/(S 3.2 Throwing power3.2.1 Effective driving voltage, ΔV; 3.3 Surface area ratio; 3.4 Galvanic corrosion; 3.4.1 Driving voltage for galvanic corrosion; 3.4.1.1 Anode potential, EA; 3.4.1.2 Cathode potential, EC, for oxygen reduction; 3.4.1.3 Cathode potential, EC, for hydrogen evolution; 3.4.2 Electrolyte resistivity; 3.4.3 Case studies for galvanic corrosion; 3.4.3.1 Active nonnoble metals in aerated, near neutral or alkaline electrolytes (Fig. 3.4A); 3.4.3.2 Active noble metal as cathode and active metal as anode in aerated, near neutral or alkaline electrolytes (Fig. 3.4B)
1.5.1.1 Passivity-related parameters for stainless steels1.5.2 Cathodic overvoltage; 1.5.2.1 Hydrogen evolution; 1.5.2.2 Oxygen reduction; 1.5.2.3 Oxygen limiting current density; 1.5.2.4 Overall cathodic current; 1.6 Summary; 1.7 Appendix; 1.7.1 Case study-design parameters for an anodic protection system; 1.7.2 Case study-design current for cathodic protection; References; Further reading; 2 Uniform Corrosion; 2.1 Model for acidic corrosion; 2.1.1 Strong acids; 2.1.2 Carbonic acid; 2.1.3 Hydrogen sulphide; 2.1.4 Organic acids; 2.1.5 Uniform corrosion of passive metals in acids
2.2 Aerated solutions2.2.1 Oxygen limiting current density; 2.2.2 Presence of chlorine; 2.2.3 Dimensionless number approach; 2.3 Summary; 2.4 Appendix; 2.4.1 Coefficient of variation, CV; 2.4.2 Corrosion rate in carbonic acid; 2.4.2.1 Corrosion mechanism in carbonic acid; 2.4.3 Corrosion rate by organic acids; 2.4.4 Corrosion rate in acidic solutions of Fe, Zn and Cu; 2.4.5 Case study: stainless steel in acetic acid; 2.4.6 Case study: stainless steel in hot acids; 2.4.7 Dimensionless number approach vs empirical Fick equation; References; Further reading; 3 Localized Corrosion; 3.1 Macrocell
3.4.3.3 Noble metal as cathode and active metal as anode in aerated, near neutral or alkaline electrolytes (Fig. 3.4B)3.4.3.4 Passive metal as cathode and active metal as anode in aerated, near neutral or alkaline electrolytes (Fig. 3.5); 3.4.3.5 Active nonnoble metals in oxygen-free acids (Fig. 3.6); 3.4.3.6 Noble or passive metal as cathode and active metal as anode in oxygen-free acids (Fig. 3.7); 3.4.4 Time dependency; 3.5 Differential aeration; 3.6 Intergranular corrosion; 3.6.1 Mechanism of intergranular corrosion; 3.6.2 Intergranular corrosion testing; 3.7 Summary; 3.8 Appendix
Summary Annotation Proposes models and equations derived from theory. It includes discussions of the estimation of main corrosion parameters for corrosion rate, electrochemical constraints, thresholds limits and initiation time. The algorithms proposed are the conjugation of theory and engineering practice resulting from research and professional activities carried out by the author for almost four decades
Notes Includes index
3.8.1 Coefficient of variation, CV
Print version record
Subject Tools -- Corrosion
Metals -- Corrosion fatigue.
TECHNOLOGY & ENGINEERING -- Mechanical.
Metals -- Corrosion fatigue
Form Electronic book
ISBN 9780081024256
0081024258