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E-book
Author Malkin, Aleksandr I͡Akovlevich.

Title Rheokinetics : rheological transformations in synthesis and reactions of oligomers and polymers / A. Ya. Malkin and S.G. Kulichikhin
Published Zug ; Oxford, CT : Huthig & Wepf, [1996]
©1996
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Description 1 online resource (326 pages) : illustrations
Contents Cover -- Table of Contents -- Chapter 1 Introduction -- 1.1 References for Chapter 1 -- Chapter 2 Rheokinetics of Linear Polymer Formation -- 2.1 General -- 2.2 Ionic Polymerization -- 2.2.1 A Direct Rheokinetic Problem -- 2.2.2 Anionic Polymerization with Varying Amounts of Active Centres -- 2.2.3 An Inverse Kinetic Problem -- 2.2.4 Experimental Methods -- 2.2.5 Anionic Polymerization of Dodecalactam -- 2.2.6 Increase of Viscosity during Anionic Polymerization with Changing Concentration of Active Centres -- 2.2.7 Anionic Polymerization of & -caprolactam -- 2.2.8 References for Section 2.2 -- 2.3 Free Radical Polymerization -- 2.3.1 Rheokinetics of the Process -- Theoretical Considerations -- 2.3.2 Steady Stage of Polymerization -- Experimental -- 2.3.3 Viscosity of the Medium -- Its Role -- 2.3.4 Gel Effect -- 2.3.5 Polymerization in Heterogeneous Medium -- 2.3.6 References for Section 2.3 -- 2.4 Polycondensation -- 2.4.1 Introduction -- 2.4.2 Rheokinetic Pattern of the Process -- 2.4.3 Experimental -- 2.4.4 References for Section 2.4 -- Chapter 3 Rheokinetics of Oligomer Curing -- 3.1 General principles -- 3.1.1 References for Section 3.1 -- 3.2 Determination of the Point of Gel Formation -- 3.2.1 References for Section 3.2 -- 3.3 Viscosity Increase to the Point of Gel Formation -- 3.3.1 References for Section 3.3 -- 3.4 Microphase Separation in Reactive Systems -- 3.4.1 References for Section 3.4 -- 3.5 Curing After the Point of Gel Formation -- 3.5.1 References for Section 3.5 -- 3.6 Rheokinetic Equations of Curing -- 3.6.1 References for Section 3.6 -- 3.7 Non-isothermal Curing -- 3.7.1 Causes of Non-isothermal Behaviour -- 3.7.2 Determination of Kinetic Constants in an Adiabatic Process -- 3.7.3 Non-isothermal Curing -- Calculations -- 3.7.4 Heat Transfer from an External Source (Linear Temperature Increase) -- 3.7.5 Curing at High Shear Rates -- 3.7.6 References for Section 3.7 -- 3.8 Structuring Peculiarities of Different Forms of Oligomers and Polymers -- 3.8.1 Curing Phenolformaldehyde Resins and Related Oligomers -- 3.8.2 Production of Polyurethanes -- 3.8.3 The Curing of Unsaturated Polyesters -- 3.8.4 Silico-organic Polymers -- 3.8.5 Amino-formaldehyde Resins -- 3.8.6 Epoxy silico-organic Oligomers -- 3.8.7 Rubber Compositions -- 3.8.8 Thermo-reactive Pol yamides -- 3.8.9 Epoxy Oligomers -- 3.8.10 References for Section 3.8 -- Chapter 4 Transformation in Polymeric Systems -- 4.1 Polymer-analogous Transformations -- 4.1.1 Transformations in the Solid Phase -- 4.1.2 Photo-viscous Effect -- 4.1.3 References for Section 4.1 -- 4.2 Gelation (Curing in Solution) -- 4.2.1 General Remarks -- 4.2.2 Antithixotropy During Gel Formation -- 4.2.3 The Role of the Solvent -- 4.2.4 Gelation Kinetics -- 4.2.5 Gelation of Plastisols -- 4.2.6 References for Section 4.2 -- 4.3 Rheolunetics of Phase Transitions -- 4.3.1 Plotting Phase Diagrams -- 4.3.2 Crystallization -- 4.3.3 Phase Transformations in Reactive Systems -- 4.3.4 References for Section 4.3 -- Subject index
Bibliography Includes bibliographical references and index
Notes Print version record
Subject Polymers -- Rheology.
Form Electronic book
Author Kulichikhin, S. G. (Sergeĭ Grigorʹevich)
Wiley InterScience (Online service)
ISBN 352761494X (electronic bk.)
3527614958
9783527614943 (electronic bk.)
9783527614950
Other Titles Reologii͡a v prot͡sessakh obrazovanii͡a i prevrashchenii͡a polimerov. English
Rheological transformations in synthesis and reactions of oligomers and polymers