| Description |
1 online resource |
| Contents |
880-01 Intro; Title page; Table of Contents; Copyright; Dedication; List of Contributors; Preface; Chapter 1. Chiral Pincer Complexes for Asymmetric Reactions; Abstract; 1.1 Introduction; 1.2 Reduction Reactions; 1.3 Borylation Reactions; 1.4 Alkynylation Reactions; 1.5 Reactions with Carbenoids; 1.6 Electrophilic Substitution Reactions; 1.7 Allylation and Propargylation of Carbonyl Compounds; 1.8 Aldol and Mannich Reactions; 1.9 Hydrophosphination and Hydroamination; 1.10 Miscellaneous Reactions; 1.11 Summary; References; Chapter 2. Well-defined Iron and Manganese Pincer Catalysts; Abstract |
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880-01/(S 6.3 Reversible Catalytic Hydrogenations of Organic Nitrogenous Molecules6.4 Catalytic Hydrogenation of π-Hydrocarbons; 6.5 Perspective on Future Contributions from the Field; References; Chapter 7. Actinide Pincer Chemistry: A New Frontier; Abstract; Acknowledgments; 7.1 Introduction; 7.2 General Synthetic Strategies for Preparing Actinide Pincer Complexes; 7.3 Synthesis, Structure, and Stoichiometric Reactivity of Actinide Pincer Complexes; 7.4 Catalytic Reactions Mediated by Actinide Pincer Complexes; 7.5 Conclusion; References |
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2.1 Introduction2.2 Hydrido Carbonyl Fe(II) PNP Pincer Complexes; 2.3 Hydrido Carbonyl Mn(I) PNP Pincer Complexes; 2.4 Conclusions and Perspectives; References; Chapter 3. The Pincer Complexes of Group 13-15 Elements: Recent Developments; Abstract; Acknowledgments; 3.1 Introduction; 3.2 Group 13 Complexes; 3.3 Group 14 Complexes; References; Chapter 4. Reduction of CO2 Mediated or Catalyzed by Pincer Complexes; Abstract; Acknowledgment; 4.1 Introduction; 4.2 Third-Row Transition Metal Systems; 4.3 Second-Row Transition Metal Systems; 4.4 First-Row Transition Metal Systems |
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4.5 Summary and OutlookReferences; Chapter 5. Mechanistic Insights and Computational Prediction of Base Metal Pincer Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions; Abstract; 5.1 Introduction; 5.2 Metal Complexes With Aromatic Pincer Ligands; 5.3 Metal Complexes With Aliphatic Pincer Ligands; 5.4 Bio-Inspired Design of Base Metal Pincer Complexes; 5.5 Conclusions; References; Chapter 6. Hydrogenation and Dehydrogenation Reactions Catalyzed by Iron Pincer Compounds; Abstract; 6.1 Introduction; 6.2 Reversible Catalytic Hydrogenations of Carbonyl Functionalities |
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Chapter 8. Complexes of NHC-Based CEC Pincer Ligands: Structural Diversity and ApplicationsAbstract; Acknowledgments; 8.1 Introduction; 8.2 Structural Diversity; 8.3 Preparation of Common Pro-ligands; 8.4 Complexation of CEC Ligands; 8.5 Applications; References; Chapter 9. Transition Metal Pincer Complexes With Chiral Imidazoline Donor(s): Synthesis and Asymmetric Catalysis; Abstract; Acknowledgments; 9.1 Introduction; 9.2 Synthesis of Transition Metal Pincer Complexes With Chiral (Imidazoline) Donor(s); 9.3 Applications to Asymmetric Catalytic Reactions; 9.4 Conclusion; References |
| Summary |
Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research-from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry-from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Online resource; title from PDF title page (EBSCO, viewed April 19, 2018) |
| Subject |
Organometallic compounds.
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Organometallic chemistry.
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Organometallic Compounds
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organometallic compound.
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SCIENCE -- Chemistry -- Organic.
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Organometallic chemistry
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Organometallic compounds
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| Form |
Electronic book
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| Author |
Morales-Morales, David, editor.
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| ISBN |
9780128129326 |
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0128129328 |
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