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Author Zvára, Ivo.

Title The inorganic radiochemistry of heavy elements : methods for studying gaseous compounds / Ivo Zvára
Published Berlin : Springer, 2008


Description 1 online resource (xxvii, 225 pages) : illustrations
Contents Experimental developments in gas-phase radiochemistry -- Physicochemical fundamentals -- Production of transactinoid elements, synthesis and transportation of compounds -- Gas-solid isothermal and thermochromatography -- Evaluation and interpretation of the experimental data -- Validity and accuracy of single atom studies
Summary "The aim of this book is to facilitate the wider use of advantageous gas phase techniques towards heavy elements. Studies of the transactinoid elements (polyvalent metals) stimulated application of their volatile halides, oxides, and oxyhalides to fast radiochemical separations. Selected results are presented here. Primarily, this book features the physico-chemical basis of experimental methods and techniques. It focuses on evaluation of the desorption energy from data of a single gas-solid chromatography experiment through calculation of desorption entropy. Heterogeneity of the column surface and its chemical modification are taken into account. Several approaches to the estimation of bulk properties of the compounds from experiments with only a few atoms are also discussed. The accuracy of the derived quantities is then analyzed using the Bayesian statistical approach." "The book is aimed at newcomers to the field as well as experts actively engaged in this area of research."--Jacket
Bibliography Includes bibliographical references and indexes
Notes Print version record
Subject Radiochemistry.
Gases -- Analysis.
Chemical kinetics.
Heavy metals.
Metals, Heavy
SCIENCE -- Chemistry -- Physical & Theoretical.
Science des matériaux.
Heavy metals
Chemical kinetics
Gases -- Analysis
Form Electronic book
LC no. 2007940367
ISBN 9781402066023