| Description |
1 online resource (xii, 190 pages) : illustrations (some color) |
| Series |
Monographs in supramolecular chemistry |
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Monographs in supramolecular chemistry.
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| Contents |
Cover -- Preface -- Contents -- Dedication -- Chapter 1 -- 1.1 Introduction -- 1.2 Crown Ether Precursor Work -- 1.2.1 Lüttringhaus' Macrocycles -- 1.2.2 Cyclo-oligomerization of Ethylene Oxide -- 1.2.3 The Furan-Acetone Tetramer -- 1.3 Pedersen's Discovery of Crown Ethers -- 1.4 Simmons' In-Out Bicyclic Amines -- 1.5 Lehn's Cryptands -- 1.6 Cram and Carbanions -- 1.7 Classes of Crown Ethers and Cryptands -- 1.8 Naturally Occurring Relatives of Crown Ethers -- 1.9 Nomenclature and its Problems -- 1.10 Toxicity of Crown Ether Compounds -- Chapter 2 -- 2.1 Introduction |
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2.2 Pedersen's First Crowns -- 2.3 Tbe Etbyleneoxy Structural Unit -- 2.4 The Template Effect -- 2.5 Early Syntheses of Crowns -- 2.5.1 Dicyclohexano-18-crown-6 -- 2.5.2 18-Crown-6 -- 2.5.3 [2.2.2]-Cryptand -- 2.6 Syntheses of Crown Ethers -- 2.6.1 Monomers, Dimers, and Trimers -- 2.6.2 Nucleophiles and Bases -- 2.6.3 Leaving Groups . -- 2.6.4 Solvents -- 2.6.5 High Dilution -- 2.6.6 General Conditions -- 2.7 Incorporation of Aromatic Subunits -- 2.8 Nitrogen-containing Macrocycles -- 2.8.1 Proteetion of Nitrogen -- 2.8.2 Lactam Formation Followed by Reduction |
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2.8.3 Direct Incorporation of Nitrogen -- 2.8.4 Syntheses of Lariat Ethers -- 2.8.5 Multi-armed Lariat Ethers -- 2.8.6 Heteroaromatic Sub-units -- 2.9 Crown Ethers Containing Sulfur -- 2.10 Syntheses of Cryptands -- 2.11 Spherands, Cavitands, and Carcerands -- 2.12 Summary -- Chapter 3 -- 3.1 Introduction -- 3.2 The Extraction Technique -- 3.3 Homogeneous Cation Binding Constants -- 3.3.1 Techniques for Determining Stability Constants -- 3.3.2 Variables Affecting Homogeneous Stability Constants -- 3.3.3 The Macrocyclic Effect -- 3.3.4 Enthalpy-entropy Compensation |
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3.3.5 Brief Survey of Cation Complexation Constants -- 3.4 Binding Dynamics -- 3.5 Cation Transport -- 3.6 Complexation of Organic Cations -- 3.6.1 Ammonium Cations -- 3.6.2 Chiral Recognition -- 3.6.3 Arenediazonium Cations -- 3.6.4 Hydronium Cation -- 3.6.5 Co-operative Structures -- 3.6.6 A Polymerie Ionophore -- 3.7 Molecular Complexation -- 3.8 Anions -- Chapter 4 -- 4.1 Introduction -- 4.2 Uncomplexed Crown and Cryptand Ligands -- 4.3 Simple Crown Ether Complexes of Metal Cations -- 4.3.1 Crown Complexes of Cations that Are 'Too Large' |
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4.3.2 Crown Complexes of Cations that Are 'Too Sm all' -- 4.3.3 Complexes of Functional Crown Ether Derivatives -- 4.3.4 Lariat Ether Complexes -- 4.3.5 Bibracchial Lariat Ether Complexes -- 4.4 Cryptand Complexes -- 4.4.1 Simple Cryptand (Cryptate) Complexes -- 4.4.2 Ditopie Cryptands -- 4.4.3 Inclusion vs. Exclusion Complexes -- 4.5 Crown Ether Complexes of Other Ions and Moleeules -- 4.6 Podand Complexes -- Chapter 5 -- 5.1 Introduction -- 5.2 Solubilization Phenomena -- 5.2.1 Solubilization of Salts -- 5.2.2 Crown Activated Reagents -- 5.3 Cation Deactivation |
| Summary |
Crown Ethers and Cryptands introduces the broad and basic principles of crown ether and cryptand chemistry at the advanced undergraduate, graduate and working professional level. The book provides a brief introduction, outlining the history of the field and goes on to cover syntheses, complexation of cations and molecules, complex structures, applications and recent developments. It aims to acquaint readers with the scope and principles of the field, providing a bibliography of reviews and books as reference to further reading and citations of the original literature |
| Analysis |
Physical chemistry |
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Ethers |
| Bibliography |
Includes bibliographical references (pages 178-185) and index |
| Notes |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL |
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Print version record |
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digitized 2010 HathiTrust Digital Library committed to preserve pda MiAaHDL |
| Subject |
Ethers.
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Cyclic compounds.
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Ethers
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Cyclic compounds
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Ethers
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Éthers.
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Chimie organique.
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Kroonethers.
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Ethers cycliques.
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Chimie supramoléculaire.
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Chimie physique et théorique.
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Éthers.
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Composés cycliques.
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Cryptands.
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Éthers en couronne.
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| Form |
Electronic book
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| ISBN |
9781788010917 |
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1788010914 |
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