Description |
1 online resource (477 p.) |
Contents |
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Substitution-type Electrophilic Amination Using Hydroxylamine-Derived Reagents -- 1.1 Introduction -- 1.2 Cu-Catalyzed Reactions -- 1.3 Electrophilic Amination Reactions Catalyzed by Other Transition Metals -- 1.4 Electrophilic Amination with Hydroxylamine-derived Metallanitrenes -- 1.5 Transition-Metal-Free Electrophilic Amination Reactions -- 1.6 Conclusion -- References -- Chapter 2 Remote Functionalizations Using Nitrogen Radicals in H-Atom Transfer (HAT) Reactions -- 2.1 Introduction |
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2.2 Intramolecular 1,5-H-Atom Transfer (1,5-HAT) -- 2.3 Photoinduced Strategies -- 2.3.1 Reductive Strategies -- 2.3.1.1 1,5-HAT via Iminyl Radicals -- 2.3.1.2 1,5-HAT via Amidyl and Sulfamidyl Radicals -- 2.3.2 Oxidative Strategies -- 2.3.2.1 1,5-HAT via Iminyl Radicals -- 2.3.2.2 1,5-HAT via Amidyl and Sulfamidyl Radicals -- 2.3.3 Photoinduced Bond Homolysis -- 2.4 Thermal Strategies -- 2.5 Summary and Conclusions -- References -- Chapter 3 Radical-Based C N Bond Formation in Photo/Electrochemistry -- 3.1 Introduction -- 3.2 C N Bond Formation via N-radical Species Addition |
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3.2.1 Radical Addition to C C Double/Triple Bonds -- 3.2.1.1 Amidyl Radical Addition -- 3.2.1.2 Hydrazonyl Radical Addition -- 3.2.1.3 Aminium Radical Cation Addition -- 3.2.2 Radical Species Addition to Aromatic Rings -- 3.3 Amination via N-atom Nucleophilic Addition -- 3.3.1 Aromatic C(sp2) H Bond Amination -- 3.3.2 Olefinic C(sp2) H Bond Amination -- 3.3.3 Activated C(sp3) H Bond Amination -- 3.3.3.1 Benzylic C(sp3) H Bond Amination -- 3.3.3.2 N-&rmalpha -- -C(sp3) H Bond Amination -- 3.4 Amination via Radical Cross-coupling -- 3.4.1 Aryl C(sp2) N Bond Formation via Radical Cross-coupling |
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3.4.1.1 Aryl C(sp2) N Bond Formation Using Diarylamines -- 3.4.1.2 Aryl C(sp2) N Bond Formation Using Azoles -- 3.4.2 Other C N Bond Formation via Radical Cross-coupling -- 3.5 Summary and Conclusions -- References -- Chapter 4 Propargylamines: Recent Advances in Asymmetric Synthesis and Use as Chemical Tools in Organic Chemistry -- 4.1 Introduction -- 4.2 Metal-Catalyzed Asymmetric Synthesis of Propargylamines -- 4.2.1 Enantioselective A3 Coupling -- 4.2.1.1 Enantioselective A3 Coupling Involving Primary Amines -- 4.2.1.2 Enantioselective A3 Coupling Involving Secondary Amines |
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4.2.2 Enantioselective Propargylic Amination of Propargylic Esters with Amines -- 4.2.3 Cu-Catalyzed Enantioselective Ring Opening of Alkynyl-Substituted Epoxides/Lactones/Carbonates -- 4.2.4 Enantioselective Addition of Terminal Alkynes to Enamines/Enamides -- 4.2.5 Rh/Ru-Catalyzed Enantioselective Hydrogenation of Alkynyl-Substituted Enamides/Imines -- 4.2.6 Enantioselective C-H Activation: Synthesis of Cyclic Propargylamines -- 4.3 Enzymatic Synthesis of Propargylamines -- 4.4 Photoredox Synthesis of Propargylamines -- 4.5 Organocatalyzed Asymmetric Synthesis of Propargylamines |
Notes |
Description based upon print version of record |
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4.6 Propargylamines as Building Blocks in the Synthesis of Heterocycles |
Form |
Electronic book
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Author |
Bernardi, Luca
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ISBN |
9783527826179 |
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3527826173 |
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