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Book Cover
E-book
Author Ricci, Alfredo

Title Methodologies in Amine Synthesis Challenges and Applications
Published Newark : John Wiley & Sons, Incorporated, 2021

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Description 1 online resource (477 p.)
Contents Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Substitution-type Electrophilic Amination Using Hydroxylamine-Derived Reagents -- 1.1 Introduction -- 1.2 Cu-Catalyzed Reactions -- 1.3 Electrophilic Amination Reactions Catalyzed by Other Transition Metals -- 1.4 Electrophilic Amination with Hydroxylamine-derived Metallanitrenes -- 1.5 Transition-Metal-Free Electrophilic Amination Reactions -- 1.6 Conclusion -- References -- Chapter 2 Remote Functionalizations Using Nitrogen Radicals in H-Atom Transfer (HAT) Reactions -- 2.1 Introduction
2.2 Intramolecular 1,5-H-Atom Transfer (1,5-HAT) -- 2.3 Photoinduced Strategies -- 2.3.1 Reductive Strategies -- 2.3.1.1 1,5-HAT via Iminyl Radicals -- 2.3.1.2 1,5-HAT via Amidyl and Sulfamidyl Radicals -- 2.3.2 Oxidative Strategies -- 2.3.2.1 1,5-HAT via Iminyl Radicals -- 2.3.2.2 1,5-HAT via Amidyl and Sulfamidyl Radicals -- 2.3.3 Photoinduced Bond Homolysis -- 2.4 Thermal Strategies -- 2.5 Summary and Conclusions -- References -- Chapter 3 Radical-Based C N Bond Formation in Photo/Electrochemistry -- 3.1 Introduction -- 3.2 C N Bond Formation via N-radical Species Addition
3.2.1 Radical Addition to C C Double/Triple Bonds -- 3.2.1.1 Amidyl Radical Addition -- 3.2.1.2 Hydrazonyl Radical Addition -- 3.2.1.3 Aminium Radical Cation Addition -- 3.2.2 Radical Species Addition to Aromatic Rings -- 3.3 Amination via N-atom Nucleophilic Addition -- 3.3.1 Aromatic C(sp2) H Bond Amination -- 3.3.2 Olefinic C(sp2) H Bond Amination -- 3.3.3 Activated C(sp3) H Bond Amination -- 3.3.3.1 Benzylic C(sp3) H Bond Amination -- 3.3.3.2 N-&rmalpha -- -C(sp3) H Bond Amination -- 3.4 Amination via Radical Cross-coupling -- 3.4.1 Aryl C(sp2) N Bond Formation via Radical Cross-coupling
3.4.1.1 Aryl C(sp2) N Bond Formation Using Diarylamines -- 3.4.1.2 Aryl C(sp2) N Bond Formation Using Azoles -- 3.4.2 Other C N Bond Formation via Radical Cross-coupling -- 3.5 Summary and Conclusions -- References -- Chapter 4 Propargylamines: Recent Advances in Asymmetric Synthesis and Use as Chemical Tools in Organic Chemistry -- 4.1 Introduction -- 4.2 Metal-Catalyzed Asymmetric Synthesis of Propargylamines -- 4.2.1 Enantioselective A3 Coupling -- 4.2.1.1 Enantioselective A3 Coupling Involving Primary Amines -- 4.2.1.2 Enantioselective A3 Coupling Involving Secondary Amines
4.2.2 Enantioselective Propargylic Amination of Propargylic Esters with Amines -- 4.2.3 Cu-Catalyzed Enantioselective Ring Opening of Alkynyl-Substituted Epoxides/Lactones/Carbonates -- 4.2.4 Enantioselective Addition of Terminal Alkynes to Enamines/Enamides -- 4.2.5 Rh/Ru-Catalyzed Enantioselective Hydrogenation of Alkynyl-Substituted Enamides/Imines -- 4.2.6 Enantioselective C-H Activation: Synthesis of Cyclic Propargylamines -- 4.3 Enzymatic Synthesis of Propargylamines -- 4.4 Photoredox Synthesis of Propargylamines -- 4.5 Organocatalyzed Asymmetric Synthesis of Propargylamines
Notes Description based upon print version of record
4.6 Propargylamines as Building Blocks in the Synthesis of Heterocycles
Form Electronic book
Author Bernardi, Luca
ISBN 9783527826179
3527826173