Title Palladium in Heterocyclic Chemistry A Guide for the Synthetic Chemist

Edition 2nd ed Published Burlington : Elsevier Science, 2006

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Description 1 online resource (662 p.) Series Tetrahedron organic chemistry series Tetrahedron organic chemistry series. Contents Front cover; Palladium in Heterocyclic Chemistry; Copyright page; Preface to the second edition; Preface to the first edition; Abbreviations; Contents; Chapter 1 An introduction to palladium catalysis; 1.1 Oxidative coupling/cyclization; 1.2 Cross-coupling reactions with organometallic reagents; 1.3 The Sonogashira reaction; 1.4 The Heck, intramolecular Heck, and heteroaryl Heck reactions; 1.5 Carbonylation reactions; 1.6 The Pd-catalyzed C-P bond formation; 1.7 Palladium-catalyzed C-N bond and C-O bond-forming reactions; 1.8 The Tsuji-Trost reaction; 1.9 The Wacker-type reactions 1.10 Mori-Ban, Hegedus, and Larock indole syntheses1.11 References; Chapter 2 Pyrroles; 2.1 Synthesis of pyrrolyl halides; 2.2 Oxidative coupling/cyclization; 2.3 Coupling reactions with organometallic reagents; 2.4 Sonogashira reaction; 2.5 Heck and intramolecular Heck reactions; 2.6 Carbonylation; 2.7 C-N bond formation reactions; 2.8 Miscellaneous; 2.9 References; Chapter 3 Indoles; 3.1 Synthesis of indolyl halides; 3.2 Oxidative coupling/cyclization; 3.3 Coupling reactions with organometallic reagents; 3.4 The Sonogashira coupling; 3.5 Heck couplings; 3.6 Carbonylation 3.7 C-N bond formation reactions3.8 Miscellaneous; 3.9 References; Chapter 4 Pyridines; 4.1 Synthesis of halopyridines; 4.2 Coupling reactions with organometallic reagents; 4.3 Sonogashira reaction; 4.4 Heck and intramolecular Heck reactions; 4.5 Buchwald-Hartwig aminations(C-N bond formation); 4.6 Direct C-C bond formation; 4.7 Summary; 4.8 References; Chapter 5 Thiophenes and benzo[b]thiophenes; 5.1 Preparation of halothiophenes and halobenzothiophenes; 5.2 Oxidative and reductive coupling reactions; 5.3 Cross-coupling with organometallic reagents; 5.4 Sonogashira reaction 5.5 Heck and intramolecular Heck reactions5.6 Carbonylation reactions; 5.7 Buchwald-Hartwig aminations; 5.8 Miscellaneous; 5.9 References; Chapter 6 Furans and benzo[b]furans; 6.1 Synthesis of halofurans and halobenzo[b]furans; 6.2 Oxidative coupling/cyclization; 6.3 Coupling reactions with organometallic reagents; 6.4 Sonogashira reaction; 6.5 Heck, intramolecular Heck, and heteroaryl Heck reactions; 6.6 Heteroannulation; 6.7 Carbonylation and C-N and C-O bond formation; 6.8 References; Chapter 7 Thiazoles and benzothiazoles; 7.1 Synthesis of halothiazoles 7.2 Coupling reactions with organometallic reagents7.3 Sonogashira reaction; 7.4 Heck and heteroaryl Heck reactions; 7.5 Carbonylation; 7.6 C-N bond formation; 7.7 Site selective coupling reactions; 7.8 References; Chapter 8 Oxazoles and benzoxazoles; 8.1 Introduction; 8.2 Synthesis of halooxazoles and halobenzoxazoles; 8.3 Coupling reactions with organometallic reagents; 8.4 Heck and heteroaryl Heck reactions; 8.5 Carbonylation; 8.6 Palladium-catalyzed amination; 8.7 Carbopalladation of nitriles; 8.8 Quaterfuran and Quinquifuran; 8.9 Summary; 8.10 References; Chapter 9 Imidazoles Summary Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the p Notes Description based upon print version of record 9.1 Synthesis of haloimidazoles English Subject Heterocyclic compounds -- Synthesis Organopalladium compounds. Heterocyclic compounds -- Synthesis Organopalladium compounds Inorganic Chemistry. Organic Chemistry. Chemistry. Physical Sciences & Mathematics. Form Electronic book Author Gribble, Gordon W ISBN 1280707445 9781280707445 9786610707447 6610707448 0080465846 9780080465845

ABBREV TI PALLADIUM IN HETEROCYCLIC CHEMISTRY, VOLUME 26 PALLADIUM IN HETEROCYCLIC CHEMISTRY Other Titles Tetrahedron Organic Chemistry, 26 Tetrahedron Organic Chemistry Palladium in Heterocyclic Chemistry A Guide for the Synthetic Chemist

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