| Description |
1 online resource |
| Series |
RSC green chemistry ; 41 |
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RSC green chemistry series ; 41.
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| Contents |
16.2.1 Monoalkylation of Schiff Bases Derived from Glycine16.2.2 Dialkylation of Schiff Bases Derived from Glycine; 16.2.3 Other Alkylations with Cinchona-derived PTC Catalysts; 16.2.4 Conjugate Additions with Cinchona-derived PTC Catalysts; 16.2.5 Aldol Reactions with Cinchona-derived PTC Catalysts; 16.2.6 Mannich Reactions with Cinchona-derived PTC Catalysts; 16.2.7 Darzens Reaction with Cinchona-derived PTC Catalysts; 16.2.8 Epoxidation of Enones with Cinchona-derived PTC Catalysts; 16.2.9 Other Reactions with Cinchona-derived PTC Catalysts; 16.3 Conclusions; References |
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Chapter 17 Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts 17.1 Introduction; 17.2 Design of Chiral Amine Catalysts; 17.2.1 Aldol Reactions; 17.2.2 Mannich Reactions; 17.2.3 Conjugate Additions; 17.2.4 C-O and C-N Bond Formations; 17.2.5 Halogenations; 17.3 Design of Chiral Phase-transfer Catalysts; 17.3.1 Alkylations; 17.3.2 Conjugate Additions; 17.3.3 Aldol and Mannich Reactions; 17.3.4 Strecker Reactions; 17.3.5 Oxidations; 17.4 Conclusions; References; Chapter 18 Imidazolidinones as Asymmetric Organocatalysts ; 18.1 Introduction |
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Cover; Contents; Preface; References; Part 2; Chapter 14 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Carbon Bond-forming Reactions ; 14.1 Introduction; 14.2 Catalytic Asymmetric 1,4-Addition Reactions; 14.3 Catalytic Asymmetric 1,2-Addition Reactions; 14.4 Catalytic Asymmetric Cycloaddition Reactions; 14.5 Concluding Remarks; References; Chapter 15 Nonquaternised Cinchona Alkaloid Derivatives as Asymmetric Organocatalysts for Carbon-Heteroatom Bond-forming Reactions ; 15.1 Introduction; 15.2 Hydrophosphonylation; 15.3 Epoxidation and Hydroperoxidation |
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15.4 Aziridination15.5 Lactone and Lactam Formation; 15.6 Epoxide and Aziridine Ring Opening; 15.7 Anhydride Ring Opening; 15.8 Amination; 15.8.1 Amination by Substitution; 15.8.2 Aza-Michael Addition; 15.9 Hydroxylation; 15.9.1 Carbonyl (Sa (B-Hydroxylation ; 15.9.2 Oxa-Michael Addition; 15.10 Sulfenylation; 15.10.1 (Sa (B-Sulfenylation ; 15.10.2 Sulfa-Michael Addition; 15.11 Halogenation; References; Chapter 16 Cinchona Alkaloid Derivatives as Asymmetric Phase-transfer Catalysts ; 16.1 N-Quaternised Cinchona Alkaloid Ammonium Salts; 16.2 Asymmetric Phase-transfer Catalysis (PTC) |
| Summary |
Catalysis is a fundamentally sustainable process which can be used to produce a wide range of chemicals and their intermediates. Focussing on those catalytic processes which offer the most sustainability, this two-part book explores recent developments in this field, as well as examining future challenges. Focussing on catalysis without metals or other endangered elements, each chapter covers a different type of organocatalyst. Beginning with chapters on acid and base catalysis, the book then concentrates on asymmetric catalysis. Several chapters cover pyrrolidine-based and cinchona alkaloid-based catalysts, whilst other chapters examine further organoctalysts which are constructed only from sustainable elements. Together with Sustainable Catalysis: With Non-endangered Metals, these books examine the progress in sustainable catalysis in all areas of chemistry, and are an important reference for researchers working in catalysis and green chemistry |
| Notes |
Includes index |
| Bibliography |
Includes bibliographical references at the end of each chapters and index |
| Notes |
English |
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Online resource; title from title details screen (Royal Society of Chemistry, viewed November 19, 2015) |
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Print version record |
| Subject |
Catalysis.
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Catalysis
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Sustainability.
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SCIENCE -- Chemistry -- Physical & Theoretical.
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Catalysis
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| Form |
Electronic book
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| Author |
North, Michael, 1964- editor.
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| ISBN |
9781782626435 |
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1782626433 |
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9781782627531 |
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1782627537 |
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9781523102006 |
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1523102004 |
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1782626417 |
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9781782626411 |
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