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Title Opportunities for fluoropolymers : synthesis, characterization, processing, simulation and recycling / edited by Bruno Ameduri and Sergey Fomin
Published Amsterdam : Elsevier, 2020

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Description 1 online resource (382 pages)
Series Progress in Fluorine Science series
Progress in fluorine science series.
Contents Cover -- Title -- Copyright -- Contents -- Contributors -- About the editors -- Preface -- Chapter 1 -- Semi-fluorinated aromatic ether polymers via step-growth polymerization of fluoroalkenes -- 1 -- Introduction -- 2 -- Synthesis of perfluorocyclobutyl (pfcb) aromatic ether polymers from trifluorovinyl ether-bearing monomers -- 2.1 -- Synthesis of trifluorovinyl aromatic ethers (TFVE) -- 2.2 -- Synthesis of multifunctional trifluorovinyl ether (TFVE)-bearing monomers -- 2.3 -- PFCB containing monomers for classical polymerization
2.4 -- Postpolymerization modification on PFCB aryl ether polymers -- 2.5 -- Characterization of TFVE monomers and PFCB aromatic ether polymers -- 2.5.1 -- Infrared and Raman spectroscopy of TFVE monomers and PFCB aromatic ether polymers -- 2.5.2 -- Carbon nuclear magnetic resonance (NMR) spectroscopy -- 2.5.3 -- Fluorine NMR spectroscopy -- 2.5.4 -- Differential scanning calorimetry (DSC) -- 3 -- Synthesis and characterization of perfluorocycloalkenyl (PFCA) aromatic ether polymers -- 3.1 -- Select perfluorocycloalkenyl monomers used for synthesizing PFCA aromatic ether polymers
3.1.1 -- Direct step-growth polycondensation of perfluorocycloalkenes with bisphenols -- 3.1.2 -- Step-growth polycondensation of PFCA-end capped monomers bis(AA)-type with bisphenols -- 3.1.3 -- AB-type difunctional monomers in PFCA synthesis -- 3.1.4 -- PFCA as building block toward PFCA-enchained polymer synthesis -- 4 -- Synthesis and characterization of semi-fluorinated arylene vinylene ether (FAVE) polymers -- 4.1 -- Synthesis of FAVE polymers from the step-growth polycondensation of TFVE monomers and bisphenols -- 4.1.1 -- Direct step-growth polycondensation of TFVE and bisphenols
4.1.2 -- Step-growth polycondensation of TFVE- and hydroxyl-group containing oligomers -- 4.1.3 -- Postpolymerization modification of FAVE polymers -- 4.1.4 -- Enchainment of chromophoric units in FAVE polymers -- 5 -- Conclusion -- Abbreviations -- References -- CHAPTER 2 -- Iodine transfer emulsion polymerizations of vinylidene fluoride -- 1 -- Introduction -- 2 -- Results and discussion -- 2.1 -- Experimental considerations -- 2.2 -- Pressure impact on VDF ITP in emulsion -- 2.3 -- Impact of CTA structure and concentration on particle size distributions -- 3 -- Conclusions -- References
Chapter 3 -- Fluorinated initiators, mediators, and solvents in controlled radical polymerization -- 1 -- Introduction: general aspects of controlled radical polymerization -- 2 -- Fluorinated agents in CRP -- 2.1 -- Fluorinated iniferters and chain transfer agents (for RAFT) -- 2.2 -- Fluorinated alkoxyamines and nitroxides for nitroxide mediated polymerization -- 2.3 -- Fluorinated alkyl halides and ligands for ATRP -- 3 -- Fluorine-containing macroinitiators -- 4 -- Fluorinated solvents -- 5 -- Conclusion and outlooks -- 6 -- Acknowledgments -- References
Chapter 4 -- Specifics of the Mn2(CO)10 photomediated synthesis of PVDF block copolymers
Notes Print version record
Subject Fluoropolymers.
Fluoropolymers
Form Electronic book
Author Améduri, B.
Fomin, Sergey
ISBN 9780128219584
0128219580