| Description |
1 online resource (285 p.) |
| Contents |
Intro -- Organic Nanochemistry -- Contents -- Preface -- 1 Fundamental Concepts -- 1.1 Introduction to Nanoscience and Nanotechnology -- 1.2 Nanochemistry in Action -- 1.3 Structures and Covalent Bonding of Organic Compounds -- 1.3.1 Localized Covalent Bonds and Lewis Structures -- 1.3.2 Delocalized Covalent Bonds, Conjugation, and Resonance Theory -- 1.3.3 Aromaticity and Hückel Molecular Orbital (HMO) Theory -- 1.3.4 Hyperconjugation and Orbital Interactions -- 1.4 Non-Covalent Interactions and Supramolecular Chemistry -- 1.4.1 Electrostatic Interactions Involving Ions and Dipoles |
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1.4.2 Hydrogen Bonding Interactions -- 1.4.3 Interactions Involving p-Systems -- 1.4.4 Induced-Dipole Forces -- 1.4.5 Charge-Transfer Interactions -- 1.4.6 Hydrophobic Effects -- 1.5 Solvent Effects -- 2 Synthetic Methodologies for Preparation of Organic Nanomaterials -- 2.1 Organic Synthesis for Nanotechnology -- 2.2 Planning the Synthesis -- 2.3 Useful Synthetic Methodologies for Organic Nanomaterials -- 2.3.1 Carbon-Carbon Bond Formation via Pd-Catalyzed Cross-Coupling Reactions -- 2.3.2 Carbon-Carbon Bond Formation via Other Types of Cross-Coupling Reactions |
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2.3.3 Carbon-Carbon Bond Formation through TM-Catalyzed Homocoupling Reactions -- 2.3.4 Alkene and Alkyne Metathesis Reactions -- 2.3.5 Click Reactions -- 2.3.6 Dynamic Covalent Chemistry -- 2.4 Methods for Surface Functionalization -- 3 Molecular Recognition and Supramolecular Self-Assembly -- 3.1 History of Molecular Recognition and Supramolecular Chemistry -- 3.2 Binding and Binding Constants -- 3.3 Cooperativity and Multivalency -- 3.4 Preorganization and Complementarity -- 3.5 Thermodynamic and Kinetic Selectivity -- 3.6 Common Scaffolds of Synthetic Receptors -- 3.6.1 Crown Ethers |
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3.6.2 Podands and Lariat Ethers -- 3.6.3 Spherands, Hemispherands, and Cryptaspherands -- 3.6.4 Calixarenes and Resorcinarenes -- 3.6.5 Cavitands and Carcerands -- 3.6.6 Cyclodextrins and Cucurbiturils -- 3.7 Templated Synthesis of Macrocycles -- 4 Chemistry of Carbon Nanoallotropes -- 4.1 Classification of Carbon Nanoallotropes -- 4.2 Structural Properties of C60 and C70 Fullerenes -- 4.3 Reactivities of C60 Fullerene -- 4.3.1 Nucleophilic Addition -- 4.3.2 Cycloaddition -- 4.3.3 Other Reactivities of C60 Fullerene -- 4.3.4 Organic Synthesis of C60 Fullerene -- 4.4 Chemistry of Carbon Nanotubes |
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4.4.1 Growth Mechanisms of Single-walled Carbon Nanotubes -- 4.4.2 Chirality of SWCNT -- 4.4.3 Non-Covalent Functionalization of SWCNTs -- 4.4.4 Covalent Functionalization of SWCNTs -- 4.5 Chemistry of Graphene, Graphene Oxide, and Reduced Graphene Oxide -- 4.6 Chemistry of Carbon Quantum Dots -- 4.7 Chemistry of Molecular Nanocarbons -- 4.7.1 Molecular Bowls -- 4.7.2 Carbon Nanorings and Carbon Nanobelts -- 4.7.3 Molecular Nanographenes and Nanographene Ribbons -- 5 Synthetic Molecular Devices and Machines -- 5.1 Basic Concepts of Molecular Devices and Machines |
| Notes |
Description based upon print version of record |
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5.2 Fundamentals of Photophysical and Photochemical Principles |
| Subject |
Chemistry, Organic.
|
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Nanochemistry.
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organic chemistry.
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| Form |
Electronic book
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| ISBN |
1118870697 |
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9781118870693 |
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