| Description |
1 online resource (170 pages) : illustrations |
| Series |
Horwood chemical science series |
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Horwood chemical science series.
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| Contents |
The two Reaction PathwaysThe Intimate Mechanism; The Trans Effect; Activation Parameters; Reaction Pathways from Structural Data; Cis-Effects; The Central Metal Ion; The Dissociative Pathway; Five Coordinate Complexes; Theoretical Calculations; The Application of Reaction Mechanisms to Synthesis; Carboplatin; Reactivity Patterns; Bibliography and References; Chapter 5. Isomerisation and Racemisation Reactions; Introduction; Stereochemical Topics; Absolute Configurations; Optical Rotatory Dispersion; Kinetic Data; Spectrophotometric Method; Polarimetric methods; N.m.r. Techniques |
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Mechanisms of Isomerisation and RacemisationTopological Mechanisms; Berry Pseudorotation; The Bailar Twist; Inversion and Proton Exchange at Asymmetric Nitrogen Centres; Bibliography and References; Chapter 6. Electron Transfer Reactions; Introduction; Outer Sphere Reactions; The Theory of Outer Sphere Redox Reactions; The Marcus Equation; The Inner Sphere Mechanism; The Precursor Complex; Electronic Considerations; Activation Parameters; Long Range Electron Transfer in Metalloproteins; Optical Charge Transfer; Stereoselective Electron Transfer; Intramolecular Electron Transfer |
| Summary |
Annotation This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL |
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English |
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Print version record |
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digitized 2010 HathiTrust Digital Library committed to preserve pda MiAaHDL |
| Subject |
Metal complexes.
|
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Reaction mechanisms (Chemistry)
|
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SCIENCE -- Chemistry -- Physical & Theoretical.
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Metal complexes
|
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Reaction mechanisms (Chemistry)
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Metallkomplexe
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Reaktionsmechanismus
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| Form |
Electronic book
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| ISBN |
9781613448137 |
|
1613448139 |
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9781782420637 |
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1782420630 |
|
1898563411 |
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9781898563419 |
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