Description |
1 online resource (674 p.) |
Contents |
Front Cover -- Air Pollution Calculations -- Copyright Page -- Dedication -- Contents -- Preface -- 1 Introduction -- 1.1 What is air pollution? -- 1.2 A bit of history -- 1.2.1 Black smoke -- 1.2.2 Recent history -- 1.3 The science of air pollution -- 1.4 The atmosphere -- 1.4.1 Introduction to tropospheric physics -- 1.4.2 Atmospheric pressure -- 1.4.3 Standard conditions -- 1.5 Recent trends -- 1.6 Spatial scale -- 1.6.1 Local scale -- 1.6.2 Urban scale -- 1.6.3 Regional scale -- 1.6.4 Continental scale -- 1.6.5 Global scale -- 1.7 Stressor-receptor paradigm -- 1.8 Calculation basics |
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1.8.1 Mathematics and statistics -- 1.9 Systems thinking and sustainability -- 1.10 Conclusions -- References -- 2 Characterizing air pollutants -- 2.1 The periodic table -- 2.1.1 Isotopes -- 2.2 Empirical calculations -- 2.3 Health characterization -- 2.4 Formation reactions -- 2.4.1 Formation kinetics -- 2.5 Reaction types -- 2.6 Pollutant formation processes: introduction to chemodynamics -- 2.7 Nonchemical concentrations -- References -- 3 Pollutant transformations -- 3.1 Introduction -- 3.2 The compound -- 3.3 Air pollution kinetics -- 3.3.1 Rate order and half-life |
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3.3.2 Atmospheric kinetics -- 3.4 Energy in atmospheric transformations -- 3.4.1 Thermodynamic laws, air pollution, and ecosystems -- 3.4.2 Atmospheric photochemistry -- 3.4.3 Energy and bonds -- 3.4.4 Photoabsorption -- 3.5 Atmospheric kinetics calculations -- 3.5.1 Free radicals -- 3.6 Transformation thermodynamics -- 3.6.1 Entropy and enthalpy -- References -- 4 Environmental partitioning -- 4.1 Introduction -- 4.1.1 Vapor pressure -- 4.1.2 Solubility -- 4.2 Equilibrium -- 4.2.1 Solubility constant -- 4.3 What is the Ksp for cadmium fluoride? -- 4.3.1 The partition coefficient |
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4.3.2 Fugacity -- 4.4 Partitioning and transport -- 4.4.1 Volatilization -- 4.4.2 Compartmental affinity and fugacity -- 4.5 Integrating inherent properties and substrate characteristics -- 4.6 Movement from liquid to solid phase -- 4.7 The octanol-water coefficient -- 4.7.1 Cosolvation -- 4.8 Partitioning between air and tissue -- 4.8.1 Calculating the octanol-air partition coefficient -- 4.8.2 Dynamics within an organism -- 4.8.3 Microbial partitioning -- 4.8.4 Bioconcentration and bioaccumulation factors -- 4.9 Environmental persistence -- 4.10 Conclusions -- References -- 5 Air partitioning |
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5.1 Introduction -- 5.2 Henry's law revisited -- 5.3 Movement into the atmosphere -- 5.3.1 Net exchange -- 5.3.2 Henry's law complications -- 5.4 Interfaces -- 5.5 Partitioning between air and tissue -- 5.5.1 Calculating the octanol-air partition coefficient -- 5.6 Monod equation -- 5.7 Phytopartitioning -- 5.8 Conclusions -- References -- Further reading -- 6 Physical transport of air pollutants -- 6.1 Introduction -- 6.2 Partitioning meets the laws of motion -- 6.2.1 Concentration and flux -- 6.2.2 Molecular diffusive flux -- 6.2.3 Eddy dispersion -- 6.2.4 Advection -- 6.2.5 Dispersion |
Notes |
Description based upon print version of record |
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6.2.6 Merging mass transfer and flow |
Form |
Electronic book
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ISBN |
9780443139888 |
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0443139881 |
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