Table of Contents |
| Preface | ix |
| Acknowledgments | xi |
1. | Introduction to Electrospinning | 1 |
1.1. | Electrospinning | 1 |
1.1.1. | Brief History | 2 |
1.1.2. | Electrospinning Process and Principles | 3 |
1.1.3. | Fiber Morphology | 10 |
1.2. | Characteristics of Electrospun Nanofibers | 12 |
1.3. | Improved Electrospinning Techniques | 13 |
1.4. | Fiber-Collecting Modes | 17 |
2. | Emerging Applications of Electrospun Nanofibers | 23 |
2.1. | Biomedical | 23 |
2.1.1. | Tissue Engineering Scaffolds | 23 |
2.1.2. | Blood Vessels | 24 |
2.1.3. | Bones | 27 |
2.1.4. | Cartilages | 29 |
2.1.5. | Muscles | 30 |
2.1.6. | Skins | 31 |
2.1.7. | Neural Tissues | 32 |
2.1.8. | Other Tissue Scaffolds | 34 |
2.1.9. | Wound Healing | 34 |
2.1.10. | Drug Delivery and Release Control | 37 |
2.2. | Environmental Protection | 39 |
2.2.1. | Filtration | 39 |
2.2.2. | Metal Ion Adsorption and Recovery | 41 |
2.3. | Catalyst and Enzyme Carriers | 43 |
2.3.1. | Catalysts | 43 |
2.3.2. | Enzymes | 45 |
2.4. | Sensors | 46 |
2.5. | Energy Harvest and Storage | 49 |
2.5.1. | Solar Cells | 49 |
2.5.2. | Fuel Cells | 51 |
2.5.3. | Mechanical Energy Harvesters | 52 |
2.5.4. | Lithium Ion Batteries | 53 |
2.5.5. | Supercapacitors | 56 |
2.5.6. | Hydrogen Storage | 57 |
2.6. | Other Applications | 58 |
3. | Developments in Large-Scale Nanofiber Electrospinning Systems | 61 |
3.1. | Downward Multi-Jet Electrospinning | 61 |
3.2. | Upward Needleless Electrospinning | 66 |
3.2.1. | Electrospinning Techniques | 66 |
4. | Upward Needleless Electrospinning with Disc, Ball, and Cylinder Spinnerets | 71 |
4.1. | Cylinder Electrospinning | 71 |
4.1.1. | Effects of Applied Voltage and PVA Concentration | 72 |
4.1.2. | Effect of Cylinder End Shape | 74 |
4.1.3. | Effect of Cylinder Diameter | 75 |
4.2. | Ball Electrospinning | 76 |
4.3. | Disc Electrospinning | 77 |
4.3.1. | Effects of Applied Voltage and PVA Concentration | 78 |
4.3.2. | Effect of Disc Thickness | 80 |
4.3.3. | Comparison | 81 |
5. | Upward Needleless Electrospinning with Ring and Coil Spinnerets | 83 |
5.1. | Ring Electrospinning | 83 |
5.1.1. | Single Ring | 83 |
5.1.2. | Multiple-Ring Spinnerets | 86 |
5.2. | Wire Coil Electrospinning | 87 |
5.2.1. | Conical Coil Electrospinning | 87 |
5.3. | Effects of Experimental Parameters on Fiber Quality | 89 |
5.3.1. | PVA Concentration | 89 |
5.3.2. | Applied Voltage | 90 |
5.3.3. | Collecting Distance | 91 |
5.4. | Tubular Wire Coil Electrospinning | 92 |
5.4.1. | Spinning Process | 93 |
5.4.2. | Parameters Affecting Fiber Morphology | 94 |
5.5. | Effects of Coil Shape on Needleless Electrospinning | 95 |
5.5.1. | Spinneret Length | 95 |
5.5.2. | Spiral Distance | 96 |
5.5.3. | Coil Diameter | 97 |
5.5.4. | Wire Diameter of the Coil | 98 |
5.6. | Effects of Experimental Parameters | 98 |
5.6.1. | Coil Rotating Speed | 98 |
5.6.1.1. | Applied voltage | 98 |
5.6.2. | Collecting Distance | 99 |
5.6.3. | PVA Concentration | 100 |
5.7. | Comparison | 100 |
5.7.1. | Needle and Coil Electrospinning | 100 |
5.7.2. | Multiple Rings and Coils | 104 |
5.7.3. | Comparisons of Different Nozzles | 105 |
6. | Electrical Field Analysis | 109 |
6.1. | Cylinder Electrospinning | 111 |
6.2. | Ball Electrospinning | 115 |
6.3. | Disc Electrospinning | 117 |
6.4. | Shaft-Linked Multiple Discs | 121 |
6.5. | Ring Electrospinning | 123 |
6.6. | Multiple Rings | 129 |
6.7. | Conical Wire Coil Electrospinning | 130 |
6.8. | Tubular Wire Coil | 131 |
6.9. | Comparison of Cylinder, Disc, Ring, and Coil | 132 |
6.10. | Collectors | 135 |
7. | Fiber Collection | 137 |
7.1. | Effect of Collector Shape | 137 |
7.2. | Effect of Collection Media | 139 |
7.3. | Effect of Collecting Distance | 140 |
7.4. | Effect of Air Flow | 141 |
8. | Conclusion and Outlook | |
| Index | 187 |