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Book Cover
E-book
Author Little, R. Daniel

Title Electroorganic Synthesis Festschrift for Manuel M. Baizer
Published Milton : CRC Press LLC, 1991

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Description 1 online resource (473 p.)
Contents Cover -- Half Title -- Title -- Copyright -- Preface -- Contents -- Contributors -- Publications and Patents of Manuel M. Baizer -- Manuel's Limericks and Haikus -- Anecdotes -- Mechanism -- Are Mechanistic Studies Relevant to Electroorganic Synthesis? An Example from the Reduction of 1, 1-Dinitrocyclohexane -- Information Available from Formal Oxidation Potentials of R2NX Compounds -- Mechanism of Electrochemical Synthesis of Some Sterically Hindered Compounds -- Electrochemical Induction of SRN1 Nucleophilic Substitution
Synthesis of Aromatic Chalcogeno Derivatives by Electrochemically Induced SRN1 Substitution in MeCN. Advantages and Limits of the Electrochemical Technique -- Reduction -- Electrohydrodimerization: Comparison of Acrylonitrile and Formaldehyde -- Electroreductive Hydrodimerization of Allylbenzene and Related Aromatic Olefins -- Electroreductive Coupling of Carbonyl-Type Groups with Unsaturated Systems -- The 5,6 vs the 6,5 Electroreductive Tandem Cyclization of Ketones -- Regiocontrolled Allylation of Carbonyl Compounds by Electrochemical Reduction of Allylic Halides
Electrolytic Reductions of Heptanoyl Chloride, Phthaloyl Dichloride, and Benzoyl Chloride at Carbon and Mercury Cathodes in Acetonitrile -- Stereoselective Electrochemical and Sonochemical Reductive Silylation of Geminal Dihalides -- Reduction of Alkyl Chlorides at Lead Cathodes -- Electroreduction of 9,9'-Spirobifluorene in Dimethylformamide: Preparation of Hydrogenated Products -- Electrochemical Reduction of Carbonyl Compounds Activated by a Nitrile Function. Application to 2-Cyanocycloalkanones. Some Examples of Carbon-Carbon Bond Cleavages
The Efficient Electrochemical Reduction of Aliphatic Nitro Compounds to Amines in Neutral and Basic Media at Raney Nickel and Devarda Copper Electrodes -- Reduction of Aromatic Nitro Compounds: The Fate of Arylhydroxylamines -- Oxidation -- Anodic Methoxylation of Aromatic Compounds Occurring Via the EECrCp Mechanism -- Oxidative Organic Electrochemistry: Intramolecular Enol Ether Coupling Reactions. -- Electro-lniated Oxygenation -- Anodic Oxidation of CH-Bonds in Cyclic Hydrocarbons -- Photodetoxification Via Photoelectrochemical Oxidation on Irradiated Ti02 Particles
Anodic Addition to the Ethylenic Double Bond: The Case of Inden-1-ones -- Viable One-Pot Procedures for Electrooxidative Coupling of 2,6-Di-tert-butylphenol to 2,2'6'6-Tetra-tert-butyl-1,1'-biphenol -- Direct and Indirect Anodic Oxidation of Vinyl and Allyl Arenas : Prospects for the Formation of Benzaldehydes and Arylketones by Double-Bond Cleavage -- Formation of Heterocyclic Compounds by Electrochemical Oxidation of Hetero-AIIenes in Non-Aqueous Media -- Porous Carbon Anodes in the CAVE KF·2HF Electrolyte -- Mediated Reduction and Oxidation
Summary Baizer (1914-1988) was the foremost internationally recognized authority on organic electrosynthesis. In this festschrift , derived from a memorial symposium held in Montreal, May 1990, as part of the 177th meeting of the Electrochemical Society, and also marking the 25th anniversary of electroorgan
Notes Description based upon print version of record
Form Electronic book
ISBN 9781351452984
1351452983