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Book Cover
E-book
Author Ōhashi, Yūji, 1941- author.

Title Crystalline state photoreactions : direct observation of reaction processes and metastable intermediaries / Yuji Ohashi
Published Tokyo : Springer, [2014]

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Description 1 online resource
Contents Introduction.- Crystalline State Reaction and Reaction Cavity -- Racemizations of Alkyl Groups in Cobaloxime Complex -- Characteristic Processes of Various Racemizations -- Photoisomerization of Alkyl Groups in Cobaloxime Complexes -- Control of Reactivity -- Metastable or Unstable Intermediates in Reversible Processes -- Metastable or Unstable Intermediates in Reversible Processes -- Conclusion
Summary This book focuses on a variety of photochemical reaction processes in the crystalline state. The crystalline state reaction is a new category of solid state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction processes were observed directly by X-ray and neutron diffractions. In this book, not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the unstable species of photochromic compounds and photo-excited structures are shown with colored figures of the molecular structures, with more than 200 figures. The book is an indispensable resource not only for organic, inorganic and physical chemists but also for graduate students, as it furnishes more than 300 references
Bibliography Includes bibliographical references
Notes Online resource; title from PDF title page (viewed on Feb. 27, 2014)
Subject Chemical reactions.
Crystals -- Reactivity
Solid state chemistry.
SCIENCE -- Chemistry -- Physical & Theoretical.
Chimie.
Science des matériaux.
Chemical reactions
Solid state chemistry
Form Electronic book
ISBN 9784431543732
4431543732