| Description |
1 online resource (404 pages) |
| Contents |
Front Cover; Phase Diagrams and Thermodynamic Modeling Of Solutions; Copyright; Dedication; Contents; Acknowledgments; Introduction; List of Websites; Part I: Phase Diagrams and Thermodynamics; Chapter 1: Introduction; References; List of Websites; Chapter 2: Thermodynamics Fundamentals; 2.1. The First and Second Laws of Thermodynamics; 2.1.1. Nomenclature; 2.1.2. The First Law; 2.1.3. The Second Law; 2.1.4. The Fundamental Equation of Thermodynamics; 2.2. Enthalpy; 2.2.1. ̀̀Absolute ́́Enthalpy; 2.2.2. Standard Enthalpy of Formation; 2.3. Gibbs Energy; 2.4. Equilibrium and Chemical Reactions |
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2.4.1. Equilibria Involving a Gaseous Phase2.4.2. A Note on Nonideal Gases; 2.4.3. Predominance Diagrams; 2.5. Measuring Gibbs Energy, Enthalpy and Entropy; 2.5.1. Measuring Gibbs Energy Change; 2.5.2. Measuring Enthalpy Change; 2.5.3. Measuring Entropy-The Third Law of Thermodynamics; 2.6. Gibbs Energy of a Pure Compound as a Function of Temperature; 2.7. Auxiliary Functions; 2.8. The Chemical Potential; 2.9. Some Other Useful Thermodynamic Equations; 2.9.1. The Gibbs-Duhem Equation; 2.9.2. General Auxiliary Functions; Reference; List of Websites; Chapter 3: The Gibbs Phase Rule |
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3.1. The Phase Rule and Binary Temperature-Composition Phase Diagrams3.1.1. Three-Phase Invariants in Binary Temperature-Composition Phase Diagrams; 3.2. Other Examples of Applications of the Phase Rule; Reference; Chapter 4: Fundamentals of the Thermodynamics of Solutions; 4.1. Gibbs Energy of Mixing; 4.2. Tangent Construction; 4.3. Partial Molar Properties; 4.4. Relative Partial Molar Properties; 4.4.1. A Note on Standard States; 4.5. Activity; 4.6. Ideal Raoultian Solutions; 4.7. Excess Properties; 4.8. Activity Coefficients; 4.9. Regular Solution Theory; 4.10. Multicomponent Solutions |
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5.10. Henry's Law, Raoult's Law and Standard States5.11. Single Ion Activities; 5.12. The ̀̀Activity ́́of a Solution; 5.13. Geometry of Binary Temperature-Composition Phase Diagrams; 5.14. Effects of Grain Size, Coherency, and Strain Energy; References; List of Websites; Chapter 6: Ternary Temperature-Composition Phase Diagrams; 6.1. The Ternary Composition Triangle; 6.2. Ternary Space Model; 6.3. Polythermal Projections of Liquidus Surfaces; 6.4. Ternary Isothermal Sections; 6.4.1. Topology of Ternary Isothermal Sections; 6.5. Ternary Isopleths (Constant Composition Sections) |
| Bibliography |
ReferencesList of Websites; Chapter 5: Thermodynamic Origin of Phase Diagrams; 5.1. Temperature-Composition Phase Diagrams in Systems with Complete Solid and Liquid Miscibility; 5.2. Binary Pressure-Composition Phase Diagrams; 5.3. Minima and Maxima in Two-Phase Regions; 5.4. Miscibility Gaps; 5.5. Simple Eutectic Systems; 5.5.1. Eutectic Microstructure and the Lever Rule; 5.6. Thermodynamic Origin of Simple Binary Phase Diagrams Illustrated by Regular Solution Theory; 5.7. Immiscibility-Montectics; 5.8. Intermediate Phases; 5.9. Limited Mutual Solubility-Ideal Henrian Solutions |
| Notes |
6.5.1. Quasibinary Phase Diagrams |
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Print version record |
| Subject |
Phase diagrams.
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Thermodynamics -- Mathematical models
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TECHNOLOGY & ENGINEERING -- Mechanical.
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Phase diagrams
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Thermodynamics -- Mathematical models
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| Form |
Electronic book
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| ISBN |
9780128016695 |
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0128016698 |
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