| Description |
1 online resource (291 pages) |
| Contents |
Title Page; Copyright Page; Contents; Foreword; Preface; Personal Reflection -- Nori Shinohara; Chapter 1 Introduction; 1.1 The First Experimental Evidence of Metallofullerenes; 1.2 Early Years of Metallofullerene Research; 1.3 Conventional and IUPAC Nomenclature for Metallofullerenes; References; Chapter 2 Synthesis, Extraction, and Purification; 2.1 Synthesis of Endohedral Metallofullerenes; 2.1.1 Laser-Furnace Synthesis; 2.1.2 DC Arc-Discharge Synthesis; 2.1.3 Ion Implantation Technique; 2.2 Solvent Extraction of Metallofullerenes from Primary Soot; 2.3 Purification and Isolation by HPLC |
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2.4 Fast Separation and Purification with Lewis AcidsReferences; Chapter 3 Molecular and Crystal Structures; 3.1 Endohedral or Exohedral? A Big Controversy; 3.2 Structural Analyses; 3.2.1 Confirmation on Endohedral Structures as Determined by Synchrotron X-Ray Powder Diffraction; 3.2.2 Dynamics of Metal Atoms within the Fullerene Cage; 3.2.3 C60-Based Metallofullerene: Li@C60; 3.2.4 Crystal Structures; 3.2.5 Single-Crystal Structural Characterization; References; Chapter 4 Electronic States and Structures; 4.1 Electron Transfer in Metallofullerenes |
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4.2 ESR Evidence on the Existence of Structural Isomers4.3 Electrochemistry of Metallofullerenes; 4.4 Similarity in the UV-Vis-NIR Absorption Spectra; 4.5 Fermi Levels and the Electronic Structures; 4.6 Metal-Cage Vibration within Metallofullerenes; References; Chapter 5 Carbide and Nitride Metallofullerenes; 5.1 Discovery of Carbide Metallofullerenes; 5.2 Fullerene Quantum Gyroscope: an Ideal Molecular Rotor; 5.3 Nitride Metallofullerenes; References; Chapter 6 Non-Isolated Pentagon Rule Metallofullerenes; 6.1 Isolated Pentagon Rule; 6.2 Non-IPR Metallofullerenes; References |
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Chapter 7 Oxide and Sulfide Metallofullerenes7.1 Oxide Metallofullerenes; 7.2 Sulfide Metallofullerenes; References; Chapter 8 Non-metal Endohedral Fullerenes; 8.1 Nitrogen-Containing N@C60; 8.2 Phosphorous-Containing P@C60; 8.3 Inert Gas Endohedral Fullerenes He@C60, Ne@C60, Ar@C60, Kr@C60, and Xe@C60; 8.4 Hydrogen-Containing H2@C60; 8.5 Water-Containing H2O@C60; References; Chapter 9 Scanning Tunneling Microscopy Studies of Metallofullerenes; 9.1 STM Studies of Metallofullerenes on Clean Surfaces; 9.2 Metallofullerenes as Superatom; 9.3 STM/STS Studies on Metallofullerene Layers |
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9.4 STM/STS Studies on a Single Metallofullerene MoleculeReferences; Chapter 10 Magnetic Properties of Metallofullerenes; 10.1 Magnetism of Mono-metallofullerenes; 10.2 SXAS and SXMCD Studies of Metallofullerenes; References; Chapter 11 Organic Chemistry of Metallofullerenes; 11.1 Cycloaddition Reactions; 11.1.1 Disilylation; 11.1.2 Azomethine Ylides; 11.1.3 Bingel Cyclopropanation; 11.1.4 [4+2] Diels-Alder Cycloaddition; 11.1.5 [2+2] Cycloaddition; 11.1.6 Carbenes; 11.2 Radical Addition Reactions; 11.3 Miscellaneous Reactions; 11.4 Donor-Acceptor Dyads; 11.5 Bis-adduct Formation |
| Summary |
Endohedral Metallofullerenes: Fullerenes with Metal Inside presents a comprehensive survey of the current state of knowledge on endohedral metallofullerenes, from preparation to functionalization, reactivity and applications. Following a brief historical overview, the book describes methods for synthesis, extraction, separation and purification, and provides an insight into the molecular and crystal structures. Subsequent chapters discuss various categories of endohedral metallofullerenes based on the encapsulated species, including carbides, nitrides, sulphides, oxides, non-metal and non-IPR |
| Notes |
11.6 Supramolecular Functionalization |
| Bibliography |
Includes bibliographical references at the end of each chapters and index |
| Notes |
Print version record |
| Subject |
Fullerenes.
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Fullerenes
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| Form |
Electronic book
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| Author |
Tagmatarchis, Nikos
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| LC no. |
2015028369 |
| ISBN |
9781118698013 |
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1118698010 |
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9781118697924 |
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1118697928 |
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1119942721 |
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9781119942726 |
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