| Description |
1 online resource |
| Contents |
2.2.2 Total Synthesis of (±)-Brasiliquinone B 2.2.3 Synthesis of (2212;)-Podophyllotoxin ; 2.2.4 Synthesis of Puupehenol and Related Compounds; 2.2.5 Synthesis of (2212;)-Talaumidin ; 2.2.6 Total Synthesis of (±)-Schefferine ; 2.3 TOTAL SYNTHESIS INVOLVING INTRAMOLECULAR FC ALKYLATIONS; 2.3.1 C-C Bond Formation Leading to Homocyclic Rings ; 2.3.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.3.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.4 TOTAL SYNTHESIS THROUGH TANDEM AND CASCADE PROCESSES INVOLVING FC REACTIONS |
|
2.4.1 C-C Bond Formation Leading to Homocyclic Rings 2.4.2 C-C Bond Formation Leading to Oxygen-Containing Rings ; 2.4.3 C-C Bond Formation Leading to Nitrogen-Containing Rings ; 2.5 TOTAL SYNTHESIS INVOLVING ipso-FC REACTIONS ; 2.5.1 Synthesis of (S)-(2212;)-Xylopinine ; 2.5.2 Synthesis of Garcibracteatone; 2.6 SUMMARY AND OUTLOOK; 2.7 ACKNOWLEDGMENT; ABBREVIATIONS ; REFERENCES; CHAPTER 3 CATALYTIC FRIEDEL-CRAFTS ACYLATION REACTIONS ; 3.1 INTRODUCTION AND HISTORICAL BACKGROUND; 3.2 CATALYTIC HOMOGENEOUS ACYLATIONS; 3.2.1 Metal Halides |
|
3.2.2 Perfluoroalkanoic Acids, Perfluorosulfonic Acids, and Their (Metal) Derivatives 3.2.3 Miscellaneous; 3.3 CATALYTIC HETEROGENEOUS ACYLATIONS; 3.3.1 Zeolites; 3.3.2 Clays; 3.3.3 Metal Oxides; 3.3.4 Acid-Treated Metal Oxides ; 3.3.5 Heteropoly Acids (HPAs); 3.3.6 Nafion; 3.3.7 Miscellaneous; 3.4 DIRECT PHENOL ACYLATION; 3.5 SUMMARY AND OUTLOOK; ABBREVIATIONS ; REFERENCES ; CHAPTER 4 THE USE OF QUANTUM CHEMISTRY FOR MECHANISTIC ANALYSES OF SEAr REACTIONS ; 4.1 INTRODUCTION; 4.1.1 Historical Overview of Early Quantum Chemistry Work |
|
4.1.2 Current Mechanistic Understanding Based on Kinetic and Spectroscopic Studies 4.2 THE SEAr MECHANISM: QUANTUM CHEMICAL CHARACTERIZATION IN GAS PHASE AND SOLUTION; 4.2.1 Nitration and Nitrosation; 4.2.2 Halogenation; 4.2.3 Sulfonation; 4.2.4 Friedel-Crafts Alkylations and Acylations; 4.3 PREDICTION OF RELATIVE REACTIVITY AND REGIOSELECTIVITY BASED ON QUANTUM CHEMICAL DESCRIPTORS; 4.4 QUANTUM CHEMICAL REACTIVITY PREDICTION BASED ON MODELING OF TRANSITION STATES AND INTERMEDIATES; 4.4.1 Transition State Modeling; 4.4.2 The Reaction Intermediate or Sigma-Complex Approach |
| Summary |
Organized to enable students and synthetic chemists to understand and expand on aromatic reactions covered in foundation courses, the book offers a thorough and accessible mechanistic explanation of aromatic reactions involving arene compounds. • Surveys methods used for preparing arene compounds and their transformations • Connects reactivity and methodology with mechanism • Helps readers apply aromatic reactions in a practical context by designing syntheses • Provides essential information about techniques used to determine reaction mechanisms |
| Notes |
Includes index |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record and CIP data provided by publisher |
| Subject |
Aromatic compounds.
|
|
Chemistry, Organic.
|
|
Chemistry, Organic
|
|
organic chemistry.
|
|
SCIENCE -- Chemistry -- Organic.
|
|
Organic.
|
|
Chemistry.
|
|
SCIENCE.
|
|
Aromatic compounds
|
|
Chemistry, Organic
|
| Form |
Electronic book
|
| Author |
Mortier, Jacques, 1959- editor.
|
| LC no. |
2015025134 |
| ISBN |
9781118754986 |
|
1118754980 |
|
9781118754955 |
|
1118754956 |
|
1118752015 |
|
9781118752012 |
|
