| Description |
1 online resource (431 p.) |
| Contents |
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction: Carbon Monoxide as Synthon in Organic Synthesis -- References -- Part I Carbonylations Promoted by First Row Transition Metal Catalysts -- Chapter 2 Cobalt-Catalyzed Carbonylations -- 2.1 Introduction -- 2.2 Carbon Monoxide and Its Surrogates -- 2.3 Hydroformylation of Alkenes -- 2.4 Carbonylation of Alkynes by the Pauson-Khand [2+2+1] Reaction -- 2.5 Carbonylation of Methanol -- 2.6 Carbonylation of Heterocycles -- 2.7 Carbonylation of Alkyl and Aryl Halides -- 2.8 C H Bond Carbonylations |
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2.9 Miscellaneous Co-Catalyzed Carbonylations -- 2.10 Summary and Conclusions -- References -- Chapter 3 Nickel-Catalyzed Carbonylations -- 3.1 Introduction -- 3.2 Nickel Halides in Carbonylation Reaction -- 3.3 Ni-Chelates as Precatalysts -- 3.4 Nanoparticles as Active Catalysts -- 3.5 Dinickel Complexes as Catalysts -- 3.6 Ni/AC as a Promising Heterogeneous Catalyst -- 3.7 Use of CO Surrogates with Nickel Catalysts -- 3.7.1 Metal Carbonyls as CO Surrogates -- 3.7.2 Formates as CO Surrogates -- 3.7.3 Acid or Acid Chlorides as CO Surrogates -- 3.8 Other Prominent Roles of Nickel in Carbonylation |
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3.9 Conclusion and Future Outlook -- References -- Chapter 4 Carbonylations Catalyzed by Other First Row Transition-Metal Catalysts (Manganese, Iron, Copper) -- 4.1 Introduction -- 4.2 Synthesis of Ketones -- 4.3 Synthesis of Esters -- 4.4 Synthesis of Amides -- 4.5 Synthesis of Other Products -- 4.6 Summary and Conclusions -- References -- Part II Carbonylations Promoted by Second Row Transition Metal Catalysts -- Chapter 5 Ruthenium-Catalyzed Carbonylations -- 5.1 Introduction -- 5.2 CH Activation of Nitrogen-Containing Arene Derivatives |
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5.3 Ruthenium-Catalyzed Carbonylations of Olefins and Nitroarenes -- 5.3.1 Ruthenium-Catalyzed Hydroformylations -- 5.3.2 Ruthenium-Catalyzed Alkoxycarbonylation of Olefins -- 5.3.3 Carbonylation of Nitroarenes -- 5.4 Ruthenium-Catalyzed Carbonylation of Amines and Alcohols -- 5.5 Ruthenium-Catalyzed Cyclocarbonylations -- 5.6 Ruthenium-Catalyzed Reactions Using Syngas -- 5.6.1 Fischer-Tropsch Synthesis -- 5.6.2 Synthesis of Oxo Products from Syngas -- 5.7 Synthesis of Oxo Products from H2 and CO2 -- 5.8 Conclusions -- References -- Chapter 6 Rhodium-Catalyzed Carbonylations -- 6.1 Introduction |
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6.2 Hydroformylation -- 6.2.1 Catalyst Recovery -- 6.2.2 Aqueous Biphase Hydroformylation -- 6.2.3 Enantioselective Hydroformylation -- 6.2.4 Tandem Hydroformylation -- 6.2.5 Syngas Surrogates -- 6.3 Carbonylation -- 6.4 Some Relevant Patents and Patent Applications (2015-2020) -- 6.4.1 Hydroformylation -- 6.4.2 Preparation of Acetic Acid and Similar Compounds and Derivatives -- 6.4.3 Alcohols -- 6.5 Summary and Conclusions -- References -- Chapter 7 Palladium(0)-Catalyzed Carbonylations -- 7.1 Introduction -- 7.2 Palladium(0)-Catalyzed Carbonylative Synthesis of Ester Derivatives |
| Notes |
Description based upon print version of record |
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7.2.1 Palladium(0)-Catalyzed Carbonylative Synthesis of Ester Derivatives from Aryl Halides |
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Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force. WlAbNL |
| Subject |
Carbonyl compounds -- Synthesis
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Carbonyl compounds -- Synthesis
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| Form |
Electronic book
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| ISBN |
9783527829330 |
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3527829334 |
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9783527829347 |
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3527829342 |
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