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Book Cover
Author Mulak, J.

Title The effective crystal field potential / Jacek Mulak and Zbigniew Gajek
Edition 1st ed
Published Amsterdam ; New York : Elsevier, 2000


Description 1 online resource (xiii, 303 pages) : illustrations
Contents Front Cover; The Effective Crystal Field Potential; Copyright Page; Contents; Chapter 1. Introduction; Chapter 2. Parameterization of crystal field Hamiltonian; Chapter 3. The effective crystal field potential. Chronological development of crystal field models; Chapter 4. Ionic complex or quasi-molecular cluster. Generalized product function; Chapter 5. Point charge model (PCM); Chapter 6. One-configurational model with neglecting the non-orthogonality. The charge penetration and exchange effects
Summary As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free ions. In this way, the most simplified concept of the crystal field effect or ligand field effect in the case of individual molecules can be introduced. The conventional notion of the crystal field potential is narrowed to its non-spherical part only through ignoring the dominating spherical part whi
Bibliography Includes bibliographical references (pages 263-286) and indexes
Notes Print version record
Subject Crystal field theory.
SCIENCE -- Physics -- Magnetism.
Crystal field theory
Física do estado sólido.
Form Electronic book
Author Gajek, Zbigniew.
ISBN 9780080530710