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Book Cover
E-book
Author Shao, Lixiong

Title Chemical transformations of vinylidenecyclopropanes / Lixiong Shao, Jianmei Lu, Min Shi
Published Heidelberg ; New York : Springer, ©2012

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Description 1 online resource (x, 69 pages) : illustrations
Series SpringerBriefs in molecular science, 2191-5407
SpringerBriefs in molecular science.
Contents Introduction -- Lewis or Brønsted acid-mediated transformations of VDCPs -- Transition metal-catalyzed transformation of VDCPs -- Miscellaneous analogues -- Concluding remarks and perspectives of VDCPs
Summary Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs
Analysis Chemistry
Chemistry, Organic
Catalysis
Organometallic Chemistry
Bibliography Includes bibliographical references
Subject Cyclopropane -- Synthesis
SCIENCE -- Chemistry -- Organic.
Science des matériaux.
Chimie.
Form Electronic book
Author Lu, Jianmei
Shi, Min
ISBN 9783642275739
3642275737