| Description |
1 online resource |
| Contents |
Iodine Chemistry and Applications Iodine Chemistry and Applications -- Copyright -- Contents -- List of Contributors -- Preface -- Chapter 1 Overview -- 1.1 Introduction -- 1.2 Discovery and Naming -- 1.3 Physicochemical Properties -- 1.4 Production -- 1.5 Synthesis -- 1.6 Industrial Application -- 1.7 Recycle -- 1.8 Biological Activity -- 1.9 Pharmaceuticals -- 1.10 Agrochemicals -- 1.11 Isotopes -- References -- Part I Characteristics, elemental of iodine -- Chapter 2 Physical Properties of Iodine -- References -- Chapter 3 Analytical Methods for Iodine and Iodides -- 3.1 Determination of Concentration of Iodine or Iodides in Solution -- 3.2 Raman Spectroscopic Analysis of Polyiodides -- 3.3 X-Ray Absorption Spectroscopic Analysis of Iodine and Iodides -- References -- Chapter 4 Ion Chromatography -- 4.1 General Principles and Instrumentation -- 4.2 Stationary Phases Used for IC of Iodine Species -- 4.3 Mobile Phases -- 4.4 Detection of Iodine Species in IC -- 4.5 Strong and Weak Points of IC Determinations of Iodine Species -- 4.6 Speciation Analysis Involving IC -- 4.7 Selected Problems Associated with Preanalytical Factors Influencing IC of Iodine Species -- 4.8 Storage and Preservation -- 4.9 Trends and Future Directions of Iodine Determinations by IC -- References -- Chapter 5 Inorganic Iodides -- 5.1 Introduction -- 5.2 Hydrogen Iodide -- 5.3 Hydriodic Acid -- 5.4 Sodium Iodide -- 5.5 Potassium Iodide -- 5.6 Copper (I) Iodide -- 5.7 Silver Iodide -- 5.8 Nitrogen Triiodide -- 5.9 Iodine Pentoxide -- 5.10 Interhalogen Compound of Iodine -- References -- Chapter 6 Organic Iodides -- 6.1 Introduction -- 6.2 Iodination of Aliphatic Hydrocarbons -- 6.3 Iodination of Aromatic Hydrocarbons -- 6.4 Iodination of Alkenes -- 6.5 Iodination of Alkynes -- 6.6 Halogen-Iodine Exchange of Halo Compounds -- 6.7 Iodination of Organonitrogen Compounds |
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6.8 Iodination of Alcohols -- 6.9 Iodination of Other Compounds -- References -- Chapter 7 Hypervalent Iodine -- 7.1 Introduction -- 7.2 Structures and Properties -- 7.3 Reactivity -- 7.4 Application -- 7.5 Recent Progress and Feature Outlook -- References -- Chapter 8 Iodine and Halogen Bonding -- 8.1 Introduction -- 8.2 I2 as Halogen Bonding Donor -- References -- Part II Production of iodine -- Chapter 9 History of Iodine -- Summary -- 9.1 History of Saltpeter -- 9.2 Courtois in Dijon -- 9.3 Courtois in Paris -- 9.4 Discovery of Iodine -- References -- Chapter 10 Production Process in the Past -- References -- Chapter 11 Iodine Production from Caliche -- 11.1 Introduction -- 11.2 Production Technology -- 11.3 Obtaining Iodate Solutions -- 11.4 Description of the Iodine Extraction Process -- Reference -- Chapter 12 Iodine Production from Oilfield Brine -- 12.1 Iodine Production in the United States -- References -- Chapter 13 Iodine Production from Natural Gas Brine -- 13.1 Natural Gas Brine -- 13.2 Characteristics of Brine -- 13.3 Iodine Accumulation in Brine -- 13.4 Preservation and Destruction of Brine Deposits -- 13.5 Production of Iodine from Natural Gas Brine -- References -- Chapter 14 Recycling of Iodine -- 14.1 Introduction -- 14.2 Iodine Waste from X-ray Contrast Agents -- 14.3 Iodine Waste from Polarizing Films -- 14.4 Iodine Waste from the Industry -- 14.5 Summary -- References -- Part III Synthesis of iodine compounds -- Chapter 15 Iodinating Reagents -- 15.1 Molecular Iodine -- 15.2 Iodine Chloride -- 15.3 N-Iodosuccinimide -- 15.4 1,3-Diiodo-5,5-Dimethylhydantoin -- 15.5 N-Iodosaccharin -- 15.6 Bis(pyridine)iodonium Tetrafluoroborate -- 15.7 Others -- References -- Chapter 16 Oxidizing Agents -- 16.1 Molecular Iodine -- 16.2 Inorganic Iodine Compounds -- 16.3 Organic Hypervalent Iodine Compounds -- References |
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Chapter 17 Reaction of Iodo Compounds -- 17.1 Coupling Reactions with Organic Iodides -- References -- Chapter 18 Metal Iodides-Mediated Reaction -- 18.1 Metal Iodides-Mediated Reaction -- 18.2 Metal Iodide-Mediated Reaction (SmI2) -- References -- Part IV Biological Application of iodine -- Chapter 19 Iodinated X-Ray Contrast Agents -- 19.1 Historical Aspects -- 19.2 Extracellular (Unspecific) Contrast Agents -- 19.3 Targeted Contrast Agents -- 19.4 Summary and Conclusions -- References -- Chapter 20 Iodine as Disinfectant -- 20.1 Historical Survey -- 20.2 Chemistry -- 20.3 Preparations Containing or Releasing Free Iodine -- 20.4 Organic Iodine Compounds -- 20.5 Toxicity -- 20.6 Practical Applications -- 20.7 Residual Effects of Iodine Preparations -- 20.8 Range of Action -- References -- Chapter 21 Synthetic Thyroid Hormone -- 21.1 Introduction -- 21.2 Thyroid Hormone Biosynthesis -- 21.3 Thyroid Hormone Metabolism -- 21.4 Thyroid Disease -- 21.5 Hormone Replacement Therapy -- 21.6 Synthetic Preparation of T4 -- References -- Chapter 22 Iodine Deficiency Disorders and Their Correction Using Iodized Salt and/or Iodine Supplements -- Ecology and Dietary Sources, Absorption, Metabolism and Excretion -- 22.1 Effects of Deficiency -- 22.2 Requirements and Prevalence of Iodine Deficiency Worldwide -- 22.3 Prophylaxis and Treatment -- Summary -- References -- Chapter 23 Pharmaceuticals: Therapeutic Agents -- 23.1 Introduction -- 23.2 Antiarrhythmic Agent: Amiodarone -- 23.3 Eye Drops: Idoxuridine -- References -- Chapter 24 Agrochemicals and Anthelmintics -- 24.1 Introduction -- 24.2 Herbicides -- 24.3 Fungicides -- 24.4 Insecticides -- 24.5 Anthelmintics -- 24.6 Summary -- References -- Part V Industrial Application of iodine -- Chapter 25 Diaryliodonium Salt Photoacid Generators -- 25.1 Introduction -- 25.2 Photoinduced Acid Generation |
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25.3 Photoinitiated Cationic Polymerizations -- 25.4 Photoinitiated Condensation Polymerizations -- 25.5 Imaging Using Diaryliodonium Photoacid Generators -- 25.6 Summary -- References -- Chapter 26 Polarizing Films -- 26.1 Introduction -- 26.2 Iodine and the Development of Polarized Film -- 26.3 Modern Polarizing Films -- References -- Chapter 27 Iodine in Polymer Synthesis: An Important Element for Precision Polymerizations -- 27.1 Introduction -- 27.2 Living Polymerization and Precision Polymerization -- 27.3 Iodine in Living Cationic Polymerization Cationic Polymerization: Problems in Control -- 27.4 Living Cationic Polymerization -- 27.5 Iodine in Living Radical Polymerization -- References -- Chapter 28 Iodine in Dye-Sensitized Solar Cells -- 28.1 Background -- 28.2 Iodine at the Photoelectrode -- 28.3 Iodine at the Counterelectrode -- 28.4 Iodine in the Electrolyte -- 28.5 Challenges with the Iodine-Based Redox System -- 28.6 Conclusions and Outlook -- References -- Chapter 29 Fluorinated Repellents -- 29.1 Overview of Fluorinated Repellents -- 29.2 PFOA Issues -- 29.3 Alternative Technologies -- References -- Chapter 30 Etching Gas -- 30.1 High-Performance Silicon Dioxide Etching -- 30.2 Environmentally Harmonized CF3I Plasma for Low-Damage and Highly Selective Low-k Etching -- 30.3 Experimental -- 30.4 Results and Discussion -- 30.5 Summary -- References -- Chapter 31 Other Industrial Applications -- 31.1 Catalyst -- 31.2 Stabilizer -- 31.3 Colorant -- References -- Part VI Bioinorganic chemistry and Environmental Chemistry of iodine -- Chapter 32 Iodine Bioinorganic Chemistry: Physiology, Structures, and Mechanisms -- 32.1 Introduction -- 32.2 Basic Chemistry Of Iodine and Its Compounds -- 32.3 Iodine in Seaweeds and Microbes -- 32.4 Vanadium Haloperoxidases -- 32.5 Concluding Remarks and Future Directions -- Acknowledgments |
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Abbreviations -- References -- Chapter 33 Atmospheric Chemistry of Iodine -- References -- Part 7 Radioisotope of iodine -- Chapter 34 Radioactive Iodine -- 34.1 Introduction -- 34.2 Nuclear Power Plant Accident and Radioactive Iodine -- 34.3 Properties of Radioactive Iodine -- 34.4 Pharmaceuticals and Medical Devices Containing Radioactive Iodine -- 34.5 Labeling Reaction of Pharmaceuticals Labeled with Radioactive Iodine -- 34.6 Sodium Iodide [123I, 131I] -- 34.7 Iofetamine [123I] -- 34.8 Ioflupane [123I] -- 34.9 BMIPP [123I] -- 34.10 Iobenguane [123I] -- 34.11 Iomazenil [123I] -- 34.12 Iodine [131I] Tositumomab -- 34.13 Summary and Future Perspective -- References -- Index -- Supplemental Images -- End User License Agreement |
| Summary |
Tatsuo Kaiho is the Director of Nihon Tennen Gas Co., Ltd. (Chiba, Japan), one of the most well-known iodine manufacturing companies in the world. The Director of the Society of Iodine Science, Dr. Kaiho developed novel iodine-containing materials and processes and presented independent research at many conferences, including the International Conference of Hypervalent Iodine Chemistry (2010) and the Symposium of Iodine Science (2011). Dr. Kaiho has received several awards, such as the Distinguished Chemist Award from Chiba Prefectural Government (2001) and the Society of Iodine Science Award (2012) |
| Notes |
Includes index |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record and CIP data provided by publisher |
| Subject |
Iodine.
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Iodine -- Industrial applications
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Iodine -- Therapeutic use.
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Iodine
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TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
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Iodine
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Iodine -- Therapeutic use
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| Form |
Electronic book
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| LC no. |
2014018859 |
| ISBN |
9781118878651 |
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1118878655 |
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9781118879146 |
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1118879147 |
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9781118909911 |
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1118909917 |
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1118466292 |
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9781118466292 |
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9781322200200 |
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1322200203 |
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