Description |
1 online resource : illustrations |
Contents |
880-01 Front Cover; Advances in Transition-Metal Mediated Heterocyclic Synthesis; Copyright Page; Contents; List of Contributors; Foreword; 1 Metal-Mediated Synthesis of Nonaromatic Oxacycles From Allenols; 1.1 Introduction; 1.2 Silver-Catalyzed Reactions; 1.3 Gold-Catalyzed Reactions; 1.4 Platinum-Catalyzed Reactions; 1.5 Palladium-Catalyzed Reactions; 1.6 Lanthanum-Catalyzed Reactions; 1.7 Gallium-Catalyzed Reactions; 1.8 Conclusion; References; 2 Intramolecular Diamination of Alkenes; 2.1 Introduction |
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880-01/(S 3 Synthesis of Heterocycles by Palladium-Catalyzed Carbonylative Reactions3.1 Introduction; 3.2 Palladium-Catalyzed Cyclocarbonylations Leading to Heterocycles; 3.2.1 Under Oxidative Conditions; 3.2.1.1 With Alkyne and Alkene Derivatives (Without Direct C-H Activation); 3.2.1.2 With Acetylenic C-H Activation; 3.2.1.3 With Alkenylic C-H Activation; 3.2.1.4 With Aromatic C-H Activation; 3.2.1.5 With Aliphatic C-H Activation; 3.2.1.6 With Diols, β-Amino Alcohols, Diamines, and Related Compounds; 3.2.2 Under Nonoxidative Conditions; 3.2.2.1 With Functionalized Halides |
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2.2 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intramolecular Vicinal Diamination of Alkenes2.2.1 Palladium Catalysis; 2.2.2 Other Metal Catalysis Using Iodine(III) Oxidants; 2.2.3 Copper Catalysis; 2.3 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intra-/Intermolecular Vicinal Diamination of Alkenes; 2.3.1 Palladium Catalysis; 2.3.2 Copper Catalysis; 2.4 Metal-Catalyzed Synthesis of Heterocycles Through the Oxidative Intermolecular Vicinal Diamination of Alkenes; 2.5 Summary and Outlook; References |
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3.2.2.2 With Halides Together With Nucleophilic Partners3.2.2.3 With Halides Together With Electrophilic Partners; 3.2.2.4 With Halides Together With Alkenes and Imines; 3.2.2.5 With Halides Together With Alkynes and Arynes; 3.2.2.6 With Other Substrates; 3.3 Palladium-Catalyzed Carbonylation Processes Leading to Heterocycles Without Incorporation of CO into the Cycle; 3.3.1 Under Oxidative Conditions; 3.3.1.1 Through Carbonylative Carbocyclization; 3.3.1.2 Through Heterocyclization-Alkoxycarbonylation; 3.3.1.3 Through Heterocyclization-Carbonylation-Cyclization Coupling |
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3.3.1.4 Through Monocarbonylation of Terminal Alkynes Followed by Intramolecular Conjugate Addition3.3.2 Under Nonoxidative Conditions; 3.3.2.1 With Halides; 3.3.2.2 With Imine Derivatives; 3.3.2.3 With Functionalized Alkynes; 3.4 Conclusions and Perspectives; References; 4 Synthesis of Heterocyclic Compounds Based on Transition-Metal-Catalyzed Carbene Coupling Reactions; 4.1 Introduction; 4.2 Cyclization Prior to Metal Carbene Formation; 4.3 Cyclization Through Other Carbene Precursors; 4.4 Cyclization Through Reductive Elimination; 4.5 Cyclization Through Nucleophilic Displacement |
Summary |
Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metalsïŽto produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals |
Bibliography |
Includes bibliographical references and index |
Notes |
Online resource; title from PDF title page (EBSCO, viewed May 25, 2018) |
Subject |
Heterocyclic compounds.
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Transition metals.
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Transition metal catalysts.
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Heterocyclic Compounds
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SCIENCE -- Chemistry -- Organic.
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Heterocyclic compounds
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Transition metal catalysts
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Transition metals
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Form |
Electronic book
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Author |
Solé, Daniel, editor.
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Fernández, Israel, editor.
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ISBN |
9780128116524 |
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0128116528 |
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