| Description |
1 online resource (x, 206 pages) : illustrations (some color) |
| Series |
Advances in polymer science, 0065-3195 ; 207 |
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Advances in polymer science ; 207. 0065-3195
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| Contents |
Supramolecular polymers and networks with hydrogen bonds in the main and side-chain / W.H. Binder, R. Zirbs -- Assembly via hydrogen bonds of low molar mass compounds into supramolecular polymers / L. Bouteiller -- Supramolecular materials based on hydrogen-bonded polymers / G. ten Brinke, J. Ruokolainen, O. Ikkala -- Nanocomposites based on hydrogen bonds / H. Xu, S. Srivastava, V.M. Rotello |
| Summary |
Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic me- odsandthusgaining structuralcontrolover the?nalpolymeric materials has become feasible, resulting in the?eld of supramolecular polymer science. - sides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes -1 overawiderangeofinteractionstrengthrangingfromseveralkJmol tosev- -1 eraltensofkJmol . Centralfortheformationofthesestructuresareprecursor molecules of small molecular weight (usually lower than 10 000), which can assembleinsolidorsolutiontoaggregatesofde?nedgeometry. Intermolecular hydrogenbondsatde?nedpositionsofthesebuildingblocksaswellastheir- spectivestartinggeometryandtheinitialsizedeterminethemodeofassembly into supramolecular polymers forming network-, rodlike-,?brous-, disclike-, helical-, lamellar- and chainlike architectures. In all cases, weak to strong hydrogen-bondinginteractionscanactasthecentralstructure-directingforce fortheorganizationofpolymerchainsandthusthe?nalmaterials'properties. Theimportantcontributionofhydrogenbondstotheareaofsupramole- lar polymer chemistry is de?nitely outstanding, most of all since the potency of hydrogen-bonding systems has been found to be unique in relation to other supramolecular interactions. Thus the high level of structural diversity of many hydrogen-bonding systems as well as their high level of direction- ity and speci?city in recognition-phenomena is unbeaten in supramolecular chemistry. The realization, that their stability can be tuned over a wide range of binding strength is important for tuning the resulting material prop- ties, ranging from elastomeric to thermoplastic and even highly crosslinked duroplastic structures and networks. On the basis of the thermal reversib- ity, new materials with highly tunable properties can now be prepared, - ing able to change their mechanical and optoelectronic properties with very smallchangesofexternalstimuli. Thusthe?eldofhydrogen-bondedpolymers forms the basis for stimuli responsive and adaptable materials of the future |
| Analysis |
chemie |
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chemistry |
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biochemie |
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biochemistry |
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geneeskunde |
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medicine |
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farmacie |
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pharmacy |
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polymeren |
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polymers |
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Chemistry (General) |
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Chemie (algemeen) |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record |
| Subject |
Hydrogen bonding.
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Polymers -- Structure
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Supramolecular chemistry.
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Hydrogen Bonding
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hydrogen bonding.
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SCIENCE -- Chemistry -- Organic.
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Polymers -- Structure.
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Supramolecular chemistry.
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Hydrogen bonding.
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Science des matériaux.
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Chimie.
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Hydrogen bonding
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Polymers -- Structure
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Supramolecular chemistry
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Polymeren.
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Waterstofbruggen.
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| Form |
Electronic book
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| Author |
Binder, Wolfgang (Wolfgang H.)
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| ISBN |
9783540685883 |
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354068588X |
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9783540685876 |
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3540685871 |
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661080415X |
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9786610804153 |
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